摘要
以3-氯-2，4，6-三硝基苯胺为原料，经自偶联反应，叠氮化，脱氮环化，合成出未见报道的7-（3′-氨基-2′，4′，6′-三硝基苯基）-氨基-4，6-二硝基苯并氧化呋咱，总收率68％，采用质谱、红外、核磁共振对其进行了结构表征。利用 DSC 和 TG 研究了其热性能。结果表明，目标化合物的第一个放热分解峰温度为245．6℃，热重变化范围为150～400℃，总共失重63％。
7-（3′-Amino-2′,4′,6′-trinitrophenyl）-amino-4,6-dinitrobenzofuroxan was synthesized using 3-chloro-2,4,6-trinitro-benzenamine as primary material by self-reaction and azidcation with a total yield of 68%. Its structure was confirmed by MS,IR and 1 H NMR. Thermal behavior was studied by DSC and TG. Results show that its initial decomposition temperature is 245. 6 ℃, and the mass loss due to overall reaction（150-400 ℃）is 63%.
出处
《含能材料》
EI
CAS
CSCD
北大核心
2014年第1期124-125,共2页
Chinese Journal of Energetic Materials
