摘要
The complex DtbpNiCl2（Dtbp = 2,9-di-tert-butyl-1,10-phenanthroline） was synthe- sized and characterized by X-ray single-crystal structure analysis. For the complex： C20 H24 Cl2 N2 Ni CH2 Cl2, Mr = 506.95, monoclinic, space group P21 /c, a = 9.5905（3）, b = 13.7587（3）, c = 17.3364（5）, β = 94.244（2）°, V = 2281.31（11）3, Z = 4, Dc = 1.476 g/cm3, λ = 1.54184, μ = 5.606 mm-1, F（000） = 1048, S = 1.079, R = 0.0402 and wR = 0.1010 for 3223 observed reflections with I 〉 2σ（I）. In complex DtbpNiCl2, the nickel adopts a distorted tetrahedral geometry coordinated by two nitrogen atoms of Dtbp and two chlorine ions. The complex is connected by intermolecular C–H…Cl hydrogen bonds to form a 1D structure in the solid state.
The complex DtbpNiCl2（Dtbp = 2,9-di-tert-butyl-1,10-phenanthroline） was synthe- sized and characterized by X-ray single-crystal structure analysis. For the complex： C20 H24 Cl2 N2 Ni CH2 Cl2, Mr = 506.95, monoclinic, space group P21 /c, a = 9.5905（3）, b = 13.7587（3）, c = 17.3364（5）, β = 94.244（2）°, V = 2281.31（11）3, Z = 4, Dc = 1.476 g/cm3, λ = 1.54184, μ = 5.606 mm-1, F（000） = 1048, S = 1.079, R = 0.0402 and wR = 0.1010 for 3223 observed reflections with I 〉 2σ（I）. In complex DtbpNiCl2, the nickel adopts a distorted tetrahedral geometry coordinated by two nitrogen atoms of Dtbp and two chlorine ions. The complex is connected by intermolecular C–H…Cl hydrogen bonds to form a 1D structure in the solid state.
基金
supported by the National Natural Science Foundation of China(21102004)
the Natural Science Foundation of Anhui Higher Education Institutions of China(KJ2011A146)
