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马朗凹陷低熟页岩油地球化学特征及成烃机理 被引量:9

Geochemical Characteristics and HydrocarbonGenerating Mechanism of Low-Mature Shale Oil in Malang Sag
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摘要 勘探实践和研究表明,马朗凹陷二叠系芦草沟组源内油气为页岩油,该原油C29甾烷立体异构化参数 w(20S)/w(20S+20R)、w(ββ)/w(αα+ββ)均为0.2~0.4,为典型低熟原油。通过对芦草沟组烃源岩地球化学和有机岩石学特征的综合研究,发现低熟页岩油的生烃母质为原生的富氢无定形体,这些无定形体在沉积早期经历过细菌的改造作用,致使其具有特殊的生烃演化模式,即低熟成熟阶段早期( Ro 为0.55%~0.75%)处于生油高峰,对应埋深为1800~2900 m ,埋深大于或小于该主峰带,烃源岩生烃能力急剧降低。泥岩生烃模拟实验、热解、抽提等实验数据表明:芦草沟组低熟页岩油正是位于该主生带的源岩所生,处于生烃带的源岩区即为马朗凹陷低熟页岩油富集的有利地区。 Exploration practices and researches show that hydrocarbon in the source rocks of the Lucaogou Formation of the Permian ,Malang sag was shale oil and also a typical low-mature oil with both sterane isomerization parameters (20S/(20S + 20R) and ββ/(αα + ββ)) between 0 .2 and 0 .4 . Through comprehensive study of geochemical and organic petrology characteristics in the hydrocarbon source rock of Lucaogou Formation ,we find that the parent material of this low-mature shale oil was hydrogen-rich amorphous solid and experienced the bacteria transformation in the early sedimentary stage , w hich resulted in the formation of the particular hydrocarbon-generating evolution model . Namely ,during the low-mature and early mature stage with Ro values 0 .55% 0 .75% ,there is an oil generation peak w hose burial depth ranges from 1 800 to 2 900 m , and the hydrocarbon-generating potential of source rock drops sharply beyond the main hydrocarbon-generating zone . The results of hydrocarbon-generating simulation experiments , rock pyrolysis analysis and organic extraction of mudstone prove that the low-mature shale oil in Lucaogou Formation was generated by the hydrocarbon source rocks within the range of main hydrocarbon-generating zone ,where was the beneficial places of shale oil accumulation .
出处 《吉林大学学报(地球科学版)》 EI CAS CSCD 北大核心 2014年第1期56-66,共11页 Journal of Jilin University:Earth Science Edition
基金 国家自然科学基金青年科学基金项目(41202101)
关键词 低熟油 页岩油 主生烃带 富氢无定形体 地球化学 low-mature oil shale oil main hydrocarbon-generating zone hydrogen-rich amorphous solid geochemistry
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