摘要
The dinuclear complex [VO（L）]2（μ-O）（H2L=salicylaldehyde benzoylhydrazone） was synthesized and characterized by elemental analysis, IR, UV, cyclic voltammetry. The results showed that two oxygen atoms and one nitrogen atom of the tridentate hydrazone ligand are coordinated to vanadium（Ⅴ） atom. The vanadium atom approximates to a distorted square pyramidal coordination sphere. The redox potentials of the title complex in different solvents follow the order: CH2Cl2<CH3CN<DMF.
The dinuclear complex [VO(L)]_2(μ-O)(H_2L=salicylaldehyde benzoylhydrazone) was synthesized and characterized by elemental analysis, IR, UV, cyclic voltammetry. The results showed that two oxygen atoms and one nitrogen atom of the tridentate hydrazone ligand are coordinated to vanadium(Ⅴ) atom. The vanadium atom approximates to a distorted square pyramidal coordination sphere. The redox potentials of the title complex in different solvents follow the order: CH_2Cl_2<CH_3CN<DMF.
出处
《应用化学》
CAS
CSCD
北大核心
2001年第2期161-162,共2页
Chinese Journal of Applied Chemistry
基金
福建省自然科学基金!(B970 0 6 )
黑龙江大学青年基金
