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一种含二茂铁基水杨醛席夫碱的合成及性质表征 被引量：2

Synthesis and Characterization of a New Ferrocence-based Salicylaldehyde Sehiff-base Compound
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摘要 通过4-(2-二茂铁乙炔基)苯胺与水杨醛缩合反应得到一种新的含二茂铁基水杨醛席夫碱1,并研究了其对不同金属离子电化学及紫外-可见光谱的识别性质。结果表明,1对Cr3+有很好的紫外-可见光谱及电化学信号响应:其位于467nm的Fe(Ⅱ)→Cp的荷移光谱红移至502nm,同时Fe(Ⅲ)/Fe(Ⅱ)电位发生了～20mV的阳极移动。 A new ferrocene-containing salicylaldehyde Shiffe-base, 1, was synthesized by coupling 4-（2-fer- rocenylethynyl） phenylamine with salicylaldehyde. Its metal ions recognition ability was investigated by UV-Vis spectrometry and cyclic voltammetry （CV）. Among various metal ions, 1 shows exclusive UV-Vis and electrochemical response to Cr3＋ with a red shift from 467 to 502 nm for its low energy Fe（Ⅱ） →Cp charge transfer and a -20 mV positive shift of its Fe（ Ⅲ）/Fe（ Ⅱ） potential.
作者 邓瑞红 赵小芳 王自琛 曹迁永
机构地区 南昌大学化学系
出处 《化学世界》 CAS CSCD 北大核心 2014年第1期41-44,共4页 Chemical World
基金 国家自然科学基金项目(21162017)
关键词 二茂铁 水杨醛席夫碱 金属离子识别 ferrocene salicylaldehyde Shiff-base metal ions recognition
分类号 O627.81 [理学—有机化学]
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参考文献14

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化学世界
2014年 第1期

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