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反相液相色谱用球形共聚物柱填料 被引量:8

Spherical Copolymer as a Column Packing for Reversed-Phase Liquid Chromatography
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摘要 采用新颖聚合工艺制备用于反相高效液相色谱柱填料的乙基苯乙烯-二乙烯苯球形共聚物,不需使用备有高速搅拌的混匀器和特殊的筛析设备,聚合物粒径的95%在3~7μm之间,测算了渗透性、柱效和峰不对称性等柱参数,并通过分离实例说明该填料对胺类、酚类和芳烃类具有优良分离性能。 The spherical copolymer of ethylstyrene with divinylbenzene for using as the packing material for Reversed-phase-HPLC has been prepared by a novel polymerization process. The 95% particle sizes of the polymers are within 3-7 μm. Some column parameters such as the permeability, efficiency and peak asymmetry were calculated. The excellent characters of this packing material for the separation of mixtures of amines, phenols and aromatic hydrocarbons were well demonstrated through several examples.
机构地区 南开大学化学系
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1991年第10期1331-1334,共4页 Chemical Journal of Chinese Universities
关键词 反相液相色谱 球形聚合物 柱填料 Spherical copolymer, Reversed-phase-HPLC, Column packing material
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参考文献1

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同被引文献29

  • 1齐东来,杨新林,黄文强.蒸馏沉淀聚合过程中交联度对单分散聚合物微球形成的影响[J].离子交换与吸附,2005,21(6):481-486. 被引量:8
  • 2黄海松,徐环昕,刘坐镇,陈骏.种球溶胀法制备有机聚合物色谱填料及其在纯化红景天苷中的应用[J].华东理工大学学报(自然科学版),2007,33(4):485-488. 被引量:3
  • 3邹汉法,张卡奎,卢佩章.高效液相色谱法.第三版.北京:科学出版社,1998,10-12.
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  • 7K Li, H D H Stover. Synthesis of Monodisperse Poly (divinylben-zene) Microspheres [ J ]. J. Polym. Sci. Part A: Polym. Chem.,1993,31(13):3257- 3263.
  • 8Li K, Stover H D H. Synthesis of monodisperse poly (divinylbenzene) mierospheres [ J ]. J Polym Sci, Part A : Polym Chem, 1993,31 (13) :3257 - 3263.
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  • 10Liu Y, Hoshina K, Haqinaka J. Monodispersed, molecularly imprinted polymers for einehonidine by precipitation polymerization [ J]. Talanta,2010,80(5 ) : 1713 - 1718.

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