摘要
本文用循环伏安法和循环电流扫描计时电位法研究了中性载体ETH1616(N,N-bjs-heptylethyldiamide)推动质子在油/水界面的转移过程,探讨了有关转移过程的机理,测定了相应的扩散系数和配合物的稳定常数。
The proton transfer across the water/ nitrobenzene interface facilitated by ionophore ETH1616(N,N-bis heptyl-ethyldiamide) has been investigated by chronopotentiometry with linear current scanning and cyclic voltammetry. The stability constant of the complex and the diffusion coefficient of ionophore ETH1616 in the nitrobenzene phase have been estimated, respectively. The mechanism of the proton transfer has been discussed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1991年第9期1160-1163,共4页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
中性载体
质子转移
油
界面
水
Neutral ionophore, Water/oil interface, N,N-bis-heptyl-ethyldiamide, Proton transfer
