摘要
本文围绕近年来基于配位聚合物的纳米材料,包括配合物纳米材料和以其为前体制备的各种氧化物、硫化物等半导体材料和磁性材料的可控合成研究工作,总结了配合物纳米材料的制备方法,主要有液相法、微乳法、扩散法、界面反应法、水热/溶剂热法、高温裂解法等,以及应用方面的研究进展,并展望了配合物纳米材料今后可能的发展方向。
The progress of the controllable syntheses of the nanomaterials based on the coordination complexes is reviewed. The coordination complexes can be used as solid-state precursors for preparation of metal oxides, metal sulfides, and semiconductors, as well as hybrid earbonous nanomaterials via solid-state decomposition, solvothermal or hydrothermal reaction, mircoemulsion method, diffusion method, interfaeial reaction, microwave-assisted process, and so on. From the view of material design, the coordination complexation with different structures and compositions is a simple and rational route to synthesize novel nano-/microstructured materials. Furthermore, the development direction of nanomaterials constructed by complexes is look into the future.
出处
《化学通报》
CAS
CSCD
北大核心
2014年第1期30-36,共7页
Chemistry
基金
国家自然科学基金项目(21272118)资助
关键词
配合物
纳米材料
制备方法
应用
Coordination complexes, Nanomaterials, Synthesis methods, Application
