摘要
固体亚硝酰硝酸钌不含卤素、硫、磷等易引起催化剂中毒的元素,是制备用于煤化工行业的负载型钌催化剂的理想前驱体。以水合三氯化钌为原料,通过引入亚硝酰基、除去氯离子、萃取提纯制备了固体亚硝酰硝酸钌,适于固体亚硝酰硝酸钌的规模化合成生产。
Ruthenium（IlI） nitrosyl nitrate is a relatively catalysts used in coal chemical industry. The compound ideal precursor for preparing supported ruthenium is free of harmful elements to the catalysts such as halogens, sulfur, phosphorus. A process involves introduction of nitrosyl, removal of chloride ions and extraction of the ruthenium nitrosyl product from the reaction system. The process is acceptable for large-scale production of solid ruthenium nitrosyl nitrate.
出处
《贵金属》
CAS
CSCD
北大核心
2013年第4期33-36,共4页
Precious Metals
基金
云南省院所技术开发专项(2011CF013
2012CF003)
云南省应用基础研究项目(2010ZC250)
云锡集团科技计划项目(2012-57A)
关键词
有机化学
固体亚硝酰硝酸钌
负载型钌催化剂
合成
结构
性质
organic chemistry
solid ruthenium（III） nitrosyl nitrate
supported ruthenium catalyst
synthesis
structure
properties
