摘要
对新型配合物——苦味酸二(4-氨基-1,2,4-三唑-5-酮)四水合锰采用元素分析、FT-IR分析、粉末X射线衍射分析和单晶结构分析基础上,在线性升温条件下,用DSC,TG-DTG技术对该化合物的热分解过程进行了研究,得出了其热分解机理.
A new coordination compound of [Mn(ATO)2 (H2O)4] (PA)2 was characterized by elemental analysis, FT - DR. analysis, X - ray powder diffraction analysis and single crystal diffraction analysis. The thermal decomposition process of the title complex was studied by means of the TG - DTG and DSC under conditions of linear temperature increase. Thermal decomposition mechanism of the title coordination compound was put forward.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
2000年第12期1563-1566,共4页
Acta Chimica Sinica
关键词
制备
结构表征
ATO
苦味酸
锰配合物
热分解机理
preparation, coordination compound, structural characterization, 4 - amino - 1,2,4 - triazol -5 - one(ATO), thermal decomposition mechanism