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TC_(16)PyP(4)/AnQ混合LB膜结构的研究 被引量:1

Studies on Structure of TC_(16) PyP(4)/AnQ LB Films
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摘要 Using n [TC 16 PyP(4)]/ n (anthraquinone)(1∶1) mixture as film forming material, the film forming property of TC 16 PyP(4)/AnQ mixture on the air/water interface was studied. The structure of mixed TC 16 PyP(4)/AnQ LB films was characterized by π A isotherms, UV Vis absorption spectra and low angle X ray diffraction(LAXD). The experimental results indicate that the TC 16 PyP(4)/AnQ mixture can form a stable monolayer on the air/water interface. Most AnQ molecules are incorporated into the cavities between the long alkyl chains of TC 16 PyP(4) molecules in the mixed monolayer and LB films. Mixed TC 16 PyP(4)/AnQ monolayer can be transferred to the substrates. TC 16 PyP(4)/AnQ LB films have a good stability and periodicity. [WT5HZ] Using n [TC 16 PyP(4)]/ n (anthraquinone)(1∶1) mixture as film forming material, the film forming property of TC 16 PyP(4)/AnQ mixture on the air/water interface was studied. The structure of mixed TC 16 PyP(4)/AnQ LB films was characterized by π A isotherms, UV Vis absorption spectra and low angle X ray diffraction(LAXD). The experimental results indicate that the TC 16 PyP(4)/AnQ mixture can form a stable monolayer on the air/water interface. Most AnQ molecules are incorporated into the cavities between the long alkyl chains of TC 16 PyP(4) molecules in the mixed monolayer and LB films. Mixed TC 16 PyP(4)/AnQ monolayer can be transferred to the substrates. TC 16 PyP(4)/AnQ LB films have a good stability and periodicity. [WT5HZ]
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2000年第12期1919-1921,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金! (批准号 :5 0 0 73 0 2 5 )资助
关键词 两亲性卟啉 混合LB膜 结构 TC16PyP(4)/AnQ Amphiphilic porphyrin Mixed LB films Low angle X ray diffraction
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