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三唑-芳香多羧酸类混配金属配合物的结构与磁性能研究 被引量：3

Structures and magnetic properties of mixed triazolyl-aromatic polycarboxylate-based metal complexes
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摘要 以三唑为主配体的过渡金属配合物以其结构多样性及在磁性、吸附等功能材料中的潜在应用而成为众多科研工作者的研究热点内容之一.本文从三唑-芳香多羧酸混配配合物的合成以及芳香酸对配合物中金属-三唑次级结构的调节角度,总结了近年来报道的该类混配金属配合物的结构多样性.在此基础上,初步关联了该类混合配体顺磁金属配合物的磁-构关系. Metal-triazolate complexes have recently received intense interest due to their various structures and promising applications in adsorption and magnetism. From the viewpoints of the synthesis of the triazolyl-aromatic polycarboxylate-based metal complexes and the effect of aromatic polycarboxylate coligand on the metal-triazolate subunits, in the present paper, the structural diversities as well as the relevant magnetic properties of the reaction system were summarized based on the available crystal structures and magnetic data reported within recent years.
作者 刘忠义 刘婧 杨娜 杨恩翠 赵小军
机构地区 无机-有机杂化功能材料化学省部共建教育部重点实验室
出处 《中国科学：化学》 CAS CSCD 北大核心 2013年第10期1251-1261,共11页 SCIENTIA SINICA Chimica
基金 国家自然科学基金(21171129 21173157) 天津市教委重点项目(2012ZD02)的资助
关键词 结构多样性 磁性能 三唑-多羧基 金属配合物 structural diversity, magnetic property, triazolyl-polycarboxylate, metal complex
分类号 O641.4 [理学—物理化学]
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同被引文献13

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中国科学：化学
2013年 第10期

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