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配合物在单晶状态下二价中心金属离子交换研究进展 被引量：1

The divalent central metal ion exchange of complexes under the single crystal state
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摘要 配合物中心金属离子交换是合成异质同构配合物的重要方法,在调节配合物的药物活性、气体吸附、催化等性质以及重金属解毒方面具有潜在的应用价值.本文介绍了配合物在单晶状态下二价中心金属离子交换的研究现状、中心金属离子交换机理、交换后配合物性能改变以及配合物中心金属离子交换存在的问题,并对未来研究方向进行了展望. The center metal ion exchange is an important method to synthetic isomorphous complexes. It is of great interest for a wide range of removing toxic heavy metals and changing the properties of complexes, such as pharmacological activity, gas adsorption and catalytic, etc. This review introduced the mechanism of the center metal ion exchange in the single crystal state, explored the effect of the central metal ions on the properties of complexes, and described the existing problems and the future directions of the research briefly.
作者 吕晓锋 程龙 侯红卫
机构地区 郑州大学化学与分子工程学院
出处 《中国科学：化学》 CAS CSCD 北大核心 2013年第10期1219-1228,共10页 SCIENTIA SINICA Chimica
基金 国家自然科学基金(20971110和91022013) 高等学校博士学科点专项科研基金(20124101110002)的资助
关键词 中心金属离子交换 单晶到单晶 性能改变 center metal ion exchange, single-crystal-to-single-crystal, properties change
分类号 O641.4 [理学—物理化学]
  • 相关文献

参考文献46

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共引文献2

同被引文献79

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引证文献1

中国科学：化学
2013年 第10期

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