摘要
采用低温共沉淀-水热-煅烧法合成了锂离子电池Fe-Ni-Mn体系正极材料Li1+x(Fey/2Niy/2Mn1-y)1-x O2,并用XRD、SEM、ICP光谱和电化学性能测试对材料进行了表征。XRD测试和ICP分析表明,Fe、Ni取代Li2MnO3中的部分Mn,形成很好的固溶结构yLiFe1/2Ni1/2O2-(1-y)Li2MnO3(y=0.1,0.2,0.3,0.4,0.5)。SEM测试表明,取代量y不同,材料的表观形貌有所不同,y=0.4时材料的颗粒粒径均匀、较小,呈类球形结构。电化学性能测试表明,当y=0.4时,循环稳定性最好,充放电50次后放电比容量仍可维持在195.0 mAh/g,放电中值电压为3.5 V,y=0.4时样品在大倍率放电下的电化学性能表现良好。
Li1-x（Fey/2Niy/2Mn1-y）1-xO2 was synthesized by a coprecipitation-hydrothermal-calcinations method. The crystal structure and charge/discharge performance of Li1-x（Fey/2Niy/2Mn1-y）1-xO2 were analyzed by X-ray diffraction （XRD）, inductively coupled plasma （ICP） and electrochemical performance measurement. The XRD tests and ICP analyses demonstrate that Fe and Ni substitute a part of Mn of Li2MnO3 to form the good solid solution structure yLi1-x（Fey/2Niy/2Mn1-y）1-xO2（y= 0.1, 0.2, 0.3, 0.4, 0.5）. SEM images show that different y values lead to different apparent morphologies of the materials. When y=0.4, the particles are spherical with uniform and small size. The electrochemical tests indicate that when y=0.4, the cathode material has the best electrochemical performance with the discharge capacity of 195.0 mAh/g after 50 cycles
出处
《稀有金属材料与工程》
SCIE
EI
CAS
CSCD
北大核心
2013年第9期1869-1873,共5页
Rare Metal Materials and Engineering
基金
国家“973”重点基础研究发展规划(2009CB220100)
