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Pitzer模型对盐湖卤水体系Li^+-K^+-Mg^(2+)-SO_4^(2-)-H_2O 273.15K时溶解度的预测 被引量：4

Prediction of Solubilities for the Salt Lake System Li^+-K^+-Mg(2+)-SO_4^(2-)-H_2O at 273. 15K Using Pitzer Model
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摘要 利用文献报道的单盐溶液水的渗透系数,结合Pitzer方程,进行了Li2SO4-K2SO4-MgSO4-H2O体系的参数化工作,得到了273.15 K和298.15 K Li2SO4、K2SO4、MgSO4的单盐参数以及二离子和三离子相互作用参数。利用已获得的参数对Li2SO4-MgSO4-H2O体系、Li2SO4-K2SO4-H2O体系、K2SO4-MgSO4-H2O体系273.15 K的溶解度进行了预测,并与已有的实验数据进行了比较,获得了比较满意的结果。首次利用Pitzer模型对Li2SO4-K2SO4-MgSO4-H2O体系273.15 K的溶解度进行了预测,可靠的理论预测结果减少了繁重的实验测定工作。 Pitzer model was used to simulate the properties of the system Li2SO4-K2SO4-MgSO4-O The Pitzer binary parameters and mixture parameters for the tiffed system at 273. 15 K and 298. 15 K were ob- tained from the reliable experimental osmotic data and solubility data. The solubility isotherms of the tided three ternary systems were predicted by the Pitzer model and compared with the available expe ＂nmental data, the agreement is generally good. The solubility isotherms for the quaternary system Li2 SO4-K2 SO4- MsSO4-H2O were predicted firstly using Pitzer model. Reliable predicted results reduce the burdensomeexperimental measurements.
作者 周红艳 曾德文 韩海军 李东东
机构地区 中国科学院青海盐湖研究所 中国科学院大学
出处 《盐湖研究》 CSCD 2013年第3期49-55,共7页 Journal of Salt Lake Research
基金 中国科学院"百人计划"项目资助
关键词 硫酸锂 硫酸钾 硫酸镁 PITZER模型 溶解度 预测 Lithium sulfate Potassium sulfate Magnesium sulfate Pitzer model Solubility Prediction
分类号 O642 [理学—物理化学]
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参考文献22

  • 1Pitzer K S. Thermodynamics d electrolytes. Ⅰ. Theoretical basis and general equations [ J ]. The Journal d Physical Chemistry, 1973,77(2): 268-277.
  • 2Pitzer K S, Mayorga G. Thermodynamics of electrolytes. Ⅱ. Activity and osmotic coefficients for strong electrolytes with one or both ions univalent [ J ]. The Journal of Physical Chemistl7, 1973, 77(19): 2300-2308.
  • 3Pitzer K S, Kim J. Thermodynamics of electrolytes. Ⅳ. Ac- tivity and osmotic coeft3cients for mixed electrolytes [ J ]. Journal of the American Chemical Society, 1974, 96(18) : 5701 - 5707.
  • 4Pitzer K S. Thermodynamics of electrolytes 5: effects of higher-order electrostatic terms [ J ]. Journal of Solution Chemistry, 1975, 4(3) : 249 -265.
  • 5Pitzer K S, Leonard F. Thermodynamics of electrolytes 6: weak electrolytes including H3PO4 [ J]. Journal of Solution Chemistry, 1976, 5(4) : 269 -278.
  • 6Leonard F, Pitzer K S. Thermodynamics of electrolytes 8: high temperature properties, including enthalpy and heat capacity, with application to sodium chloride [J]. The Journal of Physical Chemistry, 1977, 81 (19): 1822 - 1828.
  • 7Pitzer K $, Leonard F. Thermodynamics of electrolytes 11 : properties of 3:2, 4:2, and other h ish-valence types [ J ]. The Journal d Physical Chemistry, 1978, 82 ( 11 ) : 1239 - 1242.
  • 8Bradley D J, Pitzer K S. Thermodyrmnfics of electrolytes. 12 : dielectric properties of water and Debye-HOckel param- eters to 350℃ 1 kbar [ J]. The Journal of Physical Chemis- try, 1979, 83(12): 1599-1603.
  • 9Pabalan R T, Pitzer K S. Thermodynandes of concenuated dectaolyte mixtures and the prediction of mineral solubilities to high temperatures for mixtures in the system Na-K-Mg-CI- SO4-OH-H2O [ J ]. Geochimica et Cosmochimica Acta, 1987, 51 (9): 2429-2443.
  • 10Pitzer K S, Wang P M, Rard J A, et al. Thermodynamics d electrolytes. 13. Ionic strength dependence d higher-order terms; Equations for CaCI2 and MgCI2[ J]. Journal of Solu- tion Chemistry, 1999, 28(4): 265 -282.

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盐湖研究
2013年 第3期

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