摘要
以苯甲醛的衍生物和异丙叉丙酮为原料合成芳姜二烯酮衍生物,然后与丙二腈类化合物进行Michael加成反应,一共合成了18种化合物,其中16种化合物均为首次报道。所有化合物结构经1H NMR,13C NMR确证。
Zingiberene derivatives were synthesized from benzaldehyde derivatives and mesityl oxide, then Michael reaction was carried out with the malononitrile derivatives in this work. A total of 18 compounds were synthesized, among which 16 had not been reported. Their structure were confirmed by ^1H NMR and ^13C NMR.
出处
《山地农业生物学报》
2013年第4期357-362,共6页
Journal of Mountain Agriculture and Biology
基金
贵州省中药现代化科技产业研究开发专项项目[黔科合中药(2012)5018号]
贵阳市科技计划项目[筑科合同(2012207)号]
贵阳市科技计划项目[筑科合同(2012303)号]
教育部"新世纪人才支持计划"[教技函(2011)95号]
贵州省优秀青年科技人才培养对象专项[黔科合人字2011(34)号]
贵阳市中药现代化项目[(2010)筑科合同字第1-中-18号]
关键词
芳姜黄酮
合成
结构修饰
羟醛缩合
迈克尔加成
Arturmerone
synthesis
structure qualification
Aldol condensation
Michael addition
