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沉积物中持久性有机物吸附解吸过程研究

Study on the adsorption-desorption behavior of persistent organic compounds in sediments
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摘要 持久性有机污染物因其高毒性、难降解性、生物累积性和长距离迁移等特性已成为沉积物中一类重要污染物,沉积物对它们的吸附-解吸行为是控制和调节水体和沉积物之间物质输送和交换的重要途径,决定了其对环境和人类的潜在威胁。本文综述了沉积物对持久性有机物的吸附解吸理论以及影响吸附-解吸行为的主要因素,包括天然有机物、有机物分子结构、pH和离子强度以及沉积物粒径等,并对当前研究中存在的问题及未来研究趋势提出建议。 Persistent organic pollutants(POPs)has become an kind of important pollutants in sediments with its high toxicity, recalcitrance,bioaccumulation features and long distance migration.The adsorption-desorption behavior is one of important unit during the process of sediment.water transport and material exchanges,and determine its potential environmental and human threats.In this paper,the theory of adsorption--desorption was reviewed with the major factors including natural organic matter,organic molocular structure,pH and ionic strength and sediment particle size.Some problems in the field as well as suggestions for future research were finally provided in this paper.
出处 《科技资讯》 2013年第15期139-140,共2页 Science & Technology Information
基金 中央级公益性科研院所基本科研业务费专项资金项目(项目编号:TKS110102)
关键词 持久性有机物 沉积物 吸附-解吸 有机质 滞后现象 Persistent organic matter,Sediments Adsorption-desorption,Organic matter Hysteresis
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  • 1杨琛,Huang Weilin,傅家谟,盛国英.煤中干酪根的成熟度与菲的吸附行为间的关系[J].地球化学,2004,33(5):528-534. 被引量:9
  • 2Bremle G iOkla L, Larsson P. Uptake of PCBs in fish in contaminated river systems:bioconcentration factors mea-sured in field[J].Environ Sci Technol, 1995,29(10):2010-2015.
  • 3Weber Jr W J,Huang W L.A distrib- uted reactivity model for sorption by soils and sediments. 4. Itraparticle het- erogeneity and phase-distribution re- lationships under nonecluilibrium conditions[J].Environ Sci Technol, 1996,30(3): 881-888.
  • 4?ignatello J J,Xing B S.Mechanisms of slow sorption organic chemicals to natural particle[J]. Environ Sci Technol, 1996,30(1).. 1-11.
  • 5Chiou C T,Kile D E, Rutherford D W, Sheng G Y,Boyd S A.Sorption of selected organic compounds from wa- ter to a peat soil and its humic-acid and humin fractions:Potential source of the sorption nonlinearity[J]. Environ Sci Technol,2000,34(7): 1254-1258.
  • 6Shi Z,Tao S,Pan B,et al.Contamina- tion of rivers in Tianjin,China by polycyclic aromatic hydrocarbons[J]. Environmental Pollution, 2005,134(1): 97-111.
  • 7舒月红,吴宏海,黄小仁,贾晓珊.CBs在沉积物上的吸附-解吸行为[J].地球化学,2009,38(2):153-158. 被引量:3
  • 8Ran Y,Xing B S,Rao PSC,Fu J. Importance of adsorption (hole-filling) mechanism for htdrophobic organic contaminants on aquifer kerogen isolate [J]. Environ Sci Technol, 2004,38(16): 4340-4348.
  • 9Wang X L,Sato T,Xing B S.Sorption and displacement of pyrene in soils and sediments[J]. Environ Sci Technol, 2005, 39(22):8712-8718.
  • 10Gao J P,Maguhn J,Spitzauer P,et al. Sorption of pesticides in the sediment of the Teufelsweiher pond(Sothern Germ any). I.. Equilibrium assements effect of organic carbon content and Ph[J].Water Res,1998,32(5).. 1662- 1672.

二级参考文献51

  • 1杨琛,Huang Weilin,傅家谟,盛国英.煤中干酪根的成熟度与菲的吸附行为间的关系[J].地球化学,2004,33(5):528-534. 被引量:9
  • 2周霞,余刚,张祖麟,牛军峰.北京通惠河水和表层沉积物中氯苯类有机物污染现状[J].环境科学,2005,26(2):117-120. 被引量:29
  • 3傅家谟 刘德汉 盛国英 等.煤成烃地球化学[M].北京:科学出版社,1992.256-257.
  • 4Huang W L, Peng P A, Yu Z Q, Fu J M. Effects of organic matter heterogeneity on sorption and desorption of organic contaminants by softs and sediments [J]. Appl Geochem, 2003, 18(7): 995-972.
  • 5Wang X L, Sato T, Xing B S. Sorption and displacement of pyrene in soils and sediments[J]. Environ Sci Technol, 2005, 39(22): 8712 -8718.
  • 6Huang W L, Weber Jr W J. A distributed reactivity model for sorption by soils and sediments. 10. Relationships between desorption, hysteresis, and the chemical characteristics of organic domains[J]. Environ Sci Technol, 1997, 31 (9) : 2562 - 2569.
  • 7Young T M, Weber Jr W J. A distributed reactivity model for sorption by soils and sediments. 3. Effects of diagenetic processes on sorption energetics[J]. Environ Sci Technol, 1995, 29(1): 92 -97.
  • 8Grathwohl P. Influence of organic matter from soils and sediments from various origins on the sorption of some chlorinated aliphatic hydrocarbons: Implications on Koc correlations [J] . Environ Sci Technol, 1990, 24(11): 1687-1693.
  • 9Xing B S, McGill W B, Dudas M J. Cross-correlation of polarity curves to predict partition coefficients of nonionic organic contaminants[J]. Environ Sci Technol, 1994, 28(11): 1929 - 1933.
  • 10Weber Jr W J, Huang W, Yu H. Hysteresis in the sorption and desorption of hydrophobic organic contaminants by soils and sediments- 2. Effects of soil organic matter heterogeneity[J] . J Contam Hydrol, 1998, 31(1): 149-165.

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