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Synthesis and properties of long-chain quaternary ammonium hydroxides 被引量:8

Synthesis and properties of long-chain quaternary ammonium hydroxides
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摘要 A series of long-chain quaternary ammonium hydroxides were synthesized from tertiary amines and confirmed by ~1H NMR and FTIR.Surface properties and pH of these surfactants were investigated.The critical micelle concentrations(CMC) of the synthesized quaternary ammonium hydroxides are lower than the conventional quaternary ammonium surfactants.The micelles shapes of these long-chain quaternary ammonium hydroxides in aqueous solution are spherical at a concentration of 0.1 mol/L.The pH values of the synthesized quaternary ammonium hydroxides are 12.25-12.51. A series of long-chain quaternary ammonium hydroxides were synthesized from tertiary amines and confirmed by ~1H NMR and FTIR.Surface properties and pH of these surfactants were investigated.The critical micelle concentrations(CMC) of the synthesized quaternary ammonium hydroxides are lower than the conventional quaternary ammonium surfactants.The micelles shapes of these long-chain quaternary ammonium hydroxides in aqueous solution are spherical at a concentration of 0.1 mol/L.The pH values of the synthesized quaternary ammonium hydroxides are 12.25-12.51.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2013年第6期494-496,共3页 中国化学快报(英文版)
基金 the financial support from Research Institute Technology Development Special Fund of Ministry of Science and Technology(No.2012EG11120)
关键词 Quaternary ammonium hydroxide Surface activity CMC The pH value Quaternary ammonium hydroxide Surface activity CMC The pH value
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