摘要
采用醚化、磷酸酯化和接枝共聚等3种方法改性魔芋下脚料中提取的絮凝活性物,用以去除废水中油脂和Cr(Ⅵ)。反应时间、用量和pH等3因子正交实验表明,经醚化改性与磷酸酯化改性后的絮凝剂分别对油脂和Cr(Ⅵ)的去除效果较好。聚合氯化铝(PAC)用量、ZnSO4用量、pH和微波照射时间等4因子正交实验表明,PAC和ZnSO4可以强化改性絮凝剂效果,对2种污染物的吸附去除效果分别用双常数方程和Elovich方程能够较好地拟合。
Using three kind of methods (etherification, phosphoric esterification, graft copolymerization) to modify the flocculating active extraction from Konjae by-products, and applying it to remove the oil and Cr( VI ) in wastewater. Orthogonal experiments with factors of reacting time, dosage and pH indicated that etherified floc- eulation and esterified flocculation can treat oil and Cr(VI) with optimum removal rate respectively. Orthogonal experiments with factors of poly-aluminum sulfate (PAC) , zinc sulfate (ZnSO4) , pH and microwave irradiation time showed that PAC and ZnSO4 can intensify flocculation effect. Using double constant equation and Elovich e- quation can fit the oil removal rate and Cr(V[) removal rate with a high de^ree of fittin~ respectively.
出处
《环境工程学报》
CAS
CSCD
北大核心
2013年第6期2179-2184,共6页
Chinese Journal of Environmental Engineering
基金
国家级大学生创新创业训练计划项目(201210635020)