期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

新型罗丹明型荧光探针的合成及其对Cu(Ⅱ)的识别性能 被引量：6

Synthesis of a Novel Rhodamine Fluorescence Probe and Its Recognition Property for Cu(Ⅱ)
在线阅读 下载PDF
导出
摘要 罗丹明B-酰肼和8-羟基-7-喹啉醛经缩合反应合成了一个新型的荧光探针(L),其结构经1H NMR,MS和元素分析表征。考察了L对金属离子的识别性能,结果表明:在乙腈溶液[V(MeCN)∶V(H2O)=19∶1,pH7.0]中,L可高选择性的识别Cu(Ⅱ)。Cu(Ⅱ)能诱导L内酰胺结构开环并形成1∶2型的配合物L-Cu(Ⅱ),这一过程是可逆的。 A novel Rhodamine fluorescence probe （L） was synthesized by condensation reaction ot Rhodamine B hydrazide with 8-hydroxyquinoline-7-carbaldehyde. The structure was characterized by 1H NMR, MS and elemental analysis. Recognition properties of L on metal ion were investigated. The results showed that L exhibited the high selective recognition for Cu（ Ⅱ ） in the acetonitrile solution[ V（MeCN） ： V（H2O） = 19 ： 1, pH 7.0]. Upon the addition of Cu（ Ⅱ ）, the spirolactam ring of L was opened and 1 ： 2 ligand-copper complex was formed, and the recognition process was proven to be a revisible process.
作者 陈稼轩 李艳 田怡 向清祥 黄玉明
机构地区 乐山师范学院化学学院 西南大学化学化工学院
出处 《合成化学》 CAS CSCD 北大核心 2013年第3期289-293,共5页 Chinese Journal of Synthetic Chemistry
基金 四川省科技厅应用基础项目(2009JY0078) 四川省教育厅重点项目(11ZA154) 乐山市科技局重点项目(2011SZD107)
关键词 罗丹明 荧光探针 Cu(Ⅱ) 合成 识别性能 Rhodamine fluorescent probe Cu（ Ⅱ ） synthesis recognition property
分类号 O621.3 [理学—有机化学] O614.12 [理学—无机化学]
  • 相关文献

参考文献19

  • 1Tapiero H, Townsend D M, Tew K D. Trace elements in human physiology and pathology copper [ J ]. Bio- medicine & Pharmacotherapy, 2003,57 ( 9 ) : 386 - 398.
  • 2Lovstad, Vstad R A. A kinetic study on the distribu- tion of Cu ( II )-ions between albumin and transferrin [ J ]. BioMetals ,2004,17 (2) : 111 - 113.
  • 3Gunnlaugsson T, Leonard J P, Murray N S. Highly selective colorimetric naked-eye Cu ( Ⅱ ) detection u- sing an azobenzene chemosensor [ J ]. Organic Letters, 2004,6(10) :1557 - 1560.
  • 4Freedman Y E, Ronen D, Long G L. Determination of Cu and Cd content of groundwater colloids by solid sampling graphite furnace atomic absorption spectrome- try [ J ]. Environmental Science & Technology, 1996,30 (7) :2270 - 2277.
  • 5Sekaly A L R, Murimboh J, Hassan N M, et al. Ki- netic speciation of Co( Ⅱ ) ,Ni(Ⅱ ) ,Cu(Ⅱ ) ,and Zn ( Ⅱ) in model solutions and freshwaters:Lability and the electron configuration [ J ]. Environmental Science & Technology ,2002,37( 1 ) :68 - 74.
  • 6Mien L B, Siitonen P H, Thompson H C. Methods forthe determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrups, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry [ J ]. Journal of Agricultural and Food Chemistry, 1997,45 ( 1 ) : 162 - 165.
  • 7Sanchez Misiego A, Garcia-Monco Carra R M, Ambel Carracedo M P, et al. Electroanalytical determination and fractionation of copper in wine [ J ]. Journal of Ag- ricuhural and Food Chemistry, 2004,52 ( 17 ) : 5316 - 5321.
  • 8Yu C, Zhang J, Li J, et al. Fluorescent probe for cop- per( Ⅱ ) ion based on arhodamine spirolactame deriva- tive, and its application to fluorescent imaging in living cells[ J ]. Microchimica Acta, 2011,174 ( 3 ) : 247 - 255.
  • 9De Silva A P, Gunararne H Q N, Gunnlaugsson T, et al. Signaling recognition events with fluorescent sen- sors and switches [ J ]. Chemical Reviews, 1997,97 : 1515 - 1566.
  • 10Quang D T, Kim J S. Fluoro- and chromogenic che- modosimeters for heavy metal ion detection in solution and biospecimens [ J ]. Chemical Reviews, 2010,110 (10) :6280 - 6301.

二级参考文献152

共引文献64

同被引文献43

  • 1曹秋娥,徐其亨.有机荧光探针试剂的进展[J].化学试剂,1993,15(5):287-292. 被引量：4
  • 2李玉杰,王金质.三聚氯氰的生产及应用[J].化学工业与工程技术,2005,26(5):22-25. 被引量：11
  • 3QUANG D T,KIM J S. Fluoro- and chromogenie ehemo- dosimeters for heavy metal ion detection in solution and biospeeimens [ J ]. Chem. Rev. , 2010,110 ( 10 ) : 6 280- 6 301.
  • 4VULPE C,LEVINSON B,WHITNEY S, et al. Isolation of a candidate gene for menkes disease and evidence that it encodes a copper transporting ATPase [ J]. Nat. Genetics, 1993,3 ( 1 ) :7-13.
  • 5WAGGONER D J, BARTNIKAS T B, GITLIN J D. The role of copper in neurodegenerative disease [ J ]. Neurobi- ology of Disease, 1999,6 ( 4 ) : 221-230.
  • 6BARNHAM K J, BUSH A I. Metals in Alzheimer's and Parkinson's diseases[ J ]. Curr. Opin. Chem. Biol. ,2008, 12(2) :222-228.
  • 7KULKARNI A, PATIL S A, BADAMI P S. Synthesis, characterization, DNA cleavage and in vitro antimiero- bial studies of La( In ) ,Th( IV ) and VO( IV ) comple- xes with Schiff lases of eoumarin derivatives [ J ]. Eur. J. Med. Chem. ,2009,44(7) :2 904-2 912.
  • 8LIU Xiao-feng,THEIL E C. Ferritins:dynamic management of biological iron and oxygen chemistry[J].{H}Accounts of Chemical Research,2005,(3):167-175.
  • 9BRUGNARA C. Iron deficiency and erythropoiesis:new diagnostic approaches[J].{H}Clinical Chemistry,2003,(10):1573-1578.
  • 10BEARD J. Iron deficiency alters brain development and functioning[J].{H}Journal of Nutrition,2003,(5 suppi,1):1468S-1472S.

引证文献6

二级引证文献13

合成化学
2013年 第3期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部