摘要
以SnO2导电玻璃为阴极，使用循环伏安法及计时电流法研究O．1mol／L硝酸镁水溶液体系中氢氧化镁的电沉积过程，并对恒电势沉积法制备的多孔Mg（OH）2薄膜的形貌、物相及光学性质进行表征。结果表明：所得Mg（OH）2薄膜呈很明显的（011）面择优取向；随着沉积电势或初始pH值的增加，Mg（OH）2二次成核的数量增加；在沉积时间固定为10min的情况下，沉积电势为-1．2、-1．3和-1．4V的薄膜在可见光范围内（390～780nm）的平均透过率依次为90．21％、69．39％和1147．12％。
Electrodeposition process of Mg（OH）2 on SnO2 coated glass was studied by cyclic voltammetry and chronoamperometry in 0.1 mol/L aqueous magnesium nitrate solution at room temperature. Characterization of morphology, phase, optical properties of the porous Mg（OH）2 thin films was carried out by FESEM, GAXRD and UV-Vis. Results show that the thin films have （011） preferred orientation. The number of secondary nucleation increases with the increase of applied potential or solution pH. The average transmittances of the porous Mg（OH）2 films deposited at -1.2, -1.3 and -1,4 V over the visible region （390-780 nm） are 90.21%, 69.39% and 47.12% respectively.
出处
《中国有色金属学报》
EI
CAS
CSCD
北大核心
2013年第4期1086-1091,共6页
The Chinese Journal of Nonferrous Metals
关键词
氢氧化镁
薄膜
电沉积
形貌
透过率
Mg（OH）2
thin films
electrodeposition
morphology
transparency
