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7-氧-双环[2.2.1]环庚烷-2,3,5,6-四酸二酐的合成研究 被引量：2

An efficient synthesis of 7-oxabicyclo[2.2.1]heptane-2,3,5,6-tetracarboxylate
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摘要 在CuCl或CuCl2作用下,Pd(0)或PdCl2催化烯烃和多烯烃与CO进行的反应是常用的甲氧基羰基化反应。采用3,6-环氧-1,2,3,6-四氢邻苯二甲酸酐通过二甲氧基羰基化反应合成了一个新的化合物,7-氧-双环[2.2.1]环庚烷-2,3,5,6-四酸二酐。红外光谱(FT-IR)与核磁共振(1 H-NMR)证实了目标产物含呋喃结构的脂环族二酐被成功合成。 Palladium（0） and palladium（ I][ ） chloride are known to catalyze the bismethoxycarbonylation of alkenes and alknes with carbon monoxide in the presentce of CuC1 or CuCle. The present work related the facile synthesis of novel compounds, 7-Oxabicyclo[2. 2. 1]heptane-2,3,5,6-tetracarboxylate, by bismethoxycarbonylation of the double bond. IR and NMR spectra indicated that the synthesis of the furan-containing alicyclic dianhydrides was successfully performed.
作者 齐海霞 张安然 吴艳 刘峰
机构地区 南昌大学化学系 配位化学国家重点实验室
出处 《化工新型材料》 CAS CSCD 北大核心 2013年第5期91-93,共3页 New Chemical Materials
基金 国家自然科学基金(50803026 51263014) 江西省科技支撑项目(2009BGA00300) 江西省教育厅项目(GJJ12127)
关键词 呋喃 二甲氧基羰基化反应 脂环族二酐 furan, bismethoxycarbonylation,alicyclic dianhydride
分类号 O624 [理学—有机化学]
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参考文献9

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二级参考文献59

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化工新型材料
2013年 第5期

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