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亚铜配合物的光致发光与电致发光研究 被引量：4

Review on photoluminescence and electroluminescence study of copper(I) complexes
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摘要 亚铜[Cu(Ⅰ)]配合物因其低廉的价格、多样化的结构和独特的光物理性质一直备受关注.本文综述了常见磷光Cu(Ⅰ)配合物[Cu(NN)2]+、[Cu(NN)(PP)]+和(CuX)mLn(其中NN表示双齿二胺配体,PP表示二膦配体,X表示卤素,L表示含N或P配体)的光致发光与电致发光研究,揭示配合物结构与光学性质的关系,探讨近年来Cu(I)配合物在有机发光二极管(OLED)领域的应用研究新进展. Copper（I） complexes have attracted considerable interest because of their rich photophysical properties and potential applications as inexpensive, abundant materials in organic light-emitting diode （OLED）. Herein we review photoluminescence and electroluminescence study on several common copper（I） complexes [Cu（NN）2]^＋, [Cu（NN）（PP）]^＋ and （CuX）mL, （where NN indicates a chelating bisimine ligand, typically a substituted 1,10- phenanthroline; PP denotes a bisphosphine ligand, X means halide, such as I, Br, Cl and L equals a ligand that contains N or P coordination site）. The relationship between structure and photoluminescence properties of copper（I） complexes and recent progress on copper（I） complexes based OLEDs are discussed.
作者 刘小琛 刘志伟 卞祖强 黄春辉
机构地区 北京分子科学国家实验室 稀土材料化学及应用国家重点实验室 北京大学化学与分子工程学院
出处 《中国科学：化学》 CAS CSCD 北大核心 2013年第4期427-436,共10页 SCIENTIA SINICA Chimica
基金 国家高技术研究发展计划(863计划 2011AA03A407) 国家自然科学基金(20971006 90922004 21201011)的支持
关键词 亚铜配合物 光致发光 电致发光 有机发光二极管 copper（I） complex, photoluminescence, electroluminescence, organic light-emitting diode （OLED）
分类号 O641.4 [理学—物理化学]
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参考文献43

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二级参考文献7

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共引文献8

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二级引证文献4

中国科学：化学
2013年 第4期

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