摘要
近十年来,特别是近几年来,有机化学工作者将无溶剂条件下的有机化学反应提出来进行专门的研究。大量研究结果证明[1-4],许多有机化学反应可以在无溶剂下进行,取得了令人欣喜的结果。与有溶剂条件下的有机反应相比,
Methyl dihydroxyethyl allyl ammonium chloride（MDAAC）was synthesized from N-methyl diethanolamine（MDEA）and allyl chloride by the solvent-free synthesis method.The effects of reaction time,reaction temperature and reactant molar ratio on reaction conversion rate were studied.The optimum process of synthesizing MDAAC obtained by orthogonal experiment was 60 min reaction time,50℃ reaction temperature and 1∶1.3 molar ratio of MDEA and allyl chloride.The target product was purified by recrystallization and the yield of product was 97%.The structure of product was characterized by IR,1H NMR and 13C NMR.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2013年第5期1884-1889,共6页
CIESC Journal
基金
广东省部产学研项目(20120980)
广州市教育局科技项目穗教科[2013]26号
国家级大学生创新训练项目(201211078006)~~
