摘要
NH3是一种在自然界生命过程及人类社会化学化工生产过程中非常重要的小分子.近年来,在过渡金属元素(如Ir,Rh,Ru,Fe,Pd等)及主族元素(如Si,Ge,Sn等)配合物活化NH3中N—H键的研究方面取得了一系列进展.介绍这方面研究的新成果.
Activation of ammonia has received increasing attention in recent years due to its important role both in nature and industry processes. A series of transition metal （such as Ir, Rh, Ru, Fe, Pd, etc.） and main group element （such as Si, Ge, Sn, etc.） complexes have been reported to activate N--H bond of ammonia in the past three decades. This review includes the recent progresses in homogeneous N--H bond activation of ammonia by transition metal and main group element complexes.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2013年第4期738-748,共11页
Chinese Journal of Organic Chemistry
关键词
氨气
N—H键
活化
过渡金属配合物
主族元素配合物
Ammonia
N--H bond
activation
transition metal complex
main group element complex
