摘要
A series of half-titanocene chloride 2-（benzimidazol-2-yl）quinolin-8-olates C1-C6 were synthesized by treating the lithium salts of the ligand with CpTiCI3. All the complexes were characterized by 1H-NMR, 13C-NMR and elemental analyses, and the crystal structure of C3 and C6 was measured by X-ray. These half-titanocene complexes showed moderate catalytic activities toward ethylene polymerization （up to 1840 kg·mol-1（Ti）·h-1） when activated with MMAO, affording the high molecular weight polymers. And they also exhibited good activity for copolymerization of ethylene and a-olefin with low content of co-monomer.
A series of half-titanocene chloride 2-（benzimidazol-2-yl）quinolin-8-olates C1-C6 were synthesized by treating the lithium salts of the ligand with CpTiCI3. All the complexes were characterized by 1H-NMR, 13C-NMR and elemental analyses, and the crystal structure of C3 and C6 was measured by X-ray. These half-titanocene complexes showed moderate catalytic activities toward ethylene polymerization （up to 1840 kg·mol-1（Ti）·h-1） when activated with MMAO, affording the high molecular weight polymers. And they also exhibited good activity for copolymerization of ethylene and a-olefin with low content of co-monomer.
基金
supported by NSFC (No. 20904059)
Key Project of 863 Program of China(No. 2009AA034605)
