摘要
La-EDTA-Fe3O4 was prepared by a chemical co-precipitation method. The magnetic composite was characterized by transmission electron microscopy （TEM）, X-ray diffraction （XRD） and Fourier transform infrared spectroscopy （FT-IR）. Furthermore, the adsorption properties of La-EDTA-Fe3O4 toward phosphate in water were investigated. The uptake rate of phosphate in water by La-EDTA-Fe3O4 was 3-1000 times than that of EDTA-Fe3O4, and reached 97.8% at 7 hr. The adsorption process agreed well with the Freundlich model and kinetics studies showed that the adsorption of phosphate proceeds according to pseudo second-order adsorption kinetics. The maximum removal rate was achieved at pH 6.0-7.0. The La-EDTA-Fe3O4 had good adsorption properties and could be separated well from aqueous solution by a permanent magnet. Therefore, this nanomaterial has potential application for the removal of phosphate from large water bodies.
La-EDTA-Fe3O4 was prepared by a chemical co-precipitation method. The magnetic composite was characterized by transmission electron microscopy （TEM）, X-ray diffraction （XRD） and Fourier transform infrared spectroscopy （FT-IR）. Furthermore, the adsorption properties of La-EDTA-Fe3O4 toward phosphate in water were investigated. The uptake rate of phosphate in water by La-EDTA-Fe3O4 was 3-1000 times than that of EDTA-Fe3O4, and reached 97.8% at 7 hr. The adsorption process agreed well with the Freundlich model and kinetics studies showed that the adsorption of phosphate proceeds according to pseudo second-order adsorption kinetics. The maximum removal rate was achieved at pH 6.0-7.0. The La-EDTA-Fe3O4 had good adsorption properties and could be separated well from aqueous solution by a permanent magnet. Therefore, this nanomaterial has potential application for the removal of phosphate from large water bodies.
基金
supported by the National Natural Science Foundation of China (No.21007014, 21107024)
the Start Foundation of Hunan Agricultural University (No.10YJ01)
the National Science and Technology Major Projects (No.2009ZX07212-001-05)
the National Environmental Protection Public Welfare Program (No.201009047)
the Scientific Research Fund of Hunan Provincial Education Department (No.11C0650)
