摘要
通过静态试验研究了高质量浓度Cl-(1000 mg.L-1)和HCO3-(2000 mg.L-1)对活性氧化铝吸附F-(10 mg.L-1)的动力学特性影响.结果表明:高质量浓度Cl-使活性氧化铝吸附F-速率加快,吸附量增加;高质量浓度HCO3-有相反趋势.建议采用活性氧化铝吸附除氟法作为煤层气产出水F-净化工艺时,考虑高质量浓度Cl-和HCO3-效应.
Activated alumina (AA) is widely used for defluoridation. Batch experiments were carried out to investigate the influence of Cl-(1000 mg· L-1) and HCO3- (2000 mg·L-1) on adsorption kinetics of F-(10 mg·L-1) on AA in coalbed methane co-produced water (CBMW). The results show that in the presence of Cl- the adsorption rate and the equilibrium absorption capacity increase, but in the presence of HCOa- both the quantities decrease. These effects should be considered when one treats CBMW.
出处
《中国科学院研究生院学报》
CAS
CSCD
北大核心
2013年第2期213-219,共7页
Journal of the Graduate School of the Chinese Academy of Sciences
基金
国家科技重大专项(2011ZX05060-005
2008ZX05039-003)资助
关键词
煤层气产出水
活性氧化铝
氟
Cl-
HCO3-
CBM co-produced water
activated alumina
fluoride
chloride ion
bicarbonate ion