摘要
A high-surface-area carbon （KC-1） was prepared from waste polystyrene-based ion exchange resin by KOH activation and used for naphthalene adsorption. The carbon exhibited a good hydrophobic nature with developed porous structure, favoring the adsorption of organic compounds. The Brunauer-Emmett-Teller surface area and total pore volume of KC- 1 were 3442.2 and 1.68 cm3/g, respectively, which can be compared with those of KOH-activated carbons prepared from other precursors. Batch experiments were carded out to investigate the adsorption of naphthalene onto KC-1. The equilibrium data were analyzed by the Langmuir, Freundlich, and Polanyi- Manes isotherms and agreed with the Polanyi-Manes Model. The adsorption of naphthalene depended greatly on the porosity of the carbon, and the dispersive interactions between naphthalene and carbon could be relatively weak. The pH variation in aqueous solution had little effect on the adsorption process. The equilibrium time for 0.04 g/L of carbon dose was around 5 hr. Different models were used to evaluate the kinetic data and the pseudo second-order model was suitable to describe the kinetic process of naphthalene adsorption onto KC-1. Regeneration of spent carbon could be carded out effectively by alcohol treatment. The results indicated that KC-1 was a promising adsorbent for the removal of polycyclic aromatic hydrocarbons from aqueous solutions.
A high-surface-area carbon （KC-1） was prepared from waste polystyrene-based ion exchange resin by KOH activation and used for naphthalene adsorption. The carbon exhibited a good hydrophobic nature with developed porous structure, favoring the adsorption of organic compounds. The Brunauer-Emmett-Teller surface area and total pore volume of KC- 1 were 3442.2 and 1.68 cm3/g, respectively, which can be compared with those of KOH-activated carbons prepared from other precursors. Batch experiments were carded out to investigate the adsorption of naphthalene onto KC-1. The equilibrium data were analyzed by the Langmuir, Freundlich, and Polanyi- Manes isotherms and agreed with the Polanyi-Manes Model. The adsorption of naphthalene depended greatly on the porosity of the carbon, and the dispersive interactions between naphthalene and carbon could be relatively weak. The pH variation in aqueous solution had little effect on the adsorption process. The equilibrium time for 0.04 g/L of carbon dose was around 5 hr. Different models were used to evaluate the kinetic data and the pseudo second-order model was suitable to describe the kinetic process of naphthalene adsorption onto KC-1. Regeneration of spent carbon could be carded out effectively by alcohol treatment. The results indicated that KC-1 was a promising adsorbent for the removal of polycyclic aromatic hydrocarbons from aqueous solutions.
基金
supported by the Program for Changjiang Scholars Innovative Research Team in University
the National Natural Science Foundation of China (No.51178215)
