摘要
Amorphous alloy Mg1.8Cu0.2Ni was successfully prepared by mechanical alloying （MA） and a series of （n-x）Ni- x（Ti＋B） composites were synthesized by MA. The electrochemical properties of Mgl.8Cu0.2Ni coated by Ni, Ti and B were studied by cyclic charge-discharge, linear polarization curve, and hydrogen diffusion coefficient experiments. Experimental results indicate that Mg1.8Cu0.2Ni-[0.9Ni0.6（Ti＋B）] composite which was MA 30 h exhibited the best performance and its initial discharge capacity arrived to 714.1 mAh/g. After 30 cycles the discharge capacity was above 530 mAh/g, which was much higher than that of Mg1.8Cu0.2Ni. And after 100 cycles it holded still 442.1 mAh/g. On all accounts, after modification by Ni, Ti and B, the initial discharge capacity and high-rate discharge ability of the electrode were evidently increased. At the same time, the cycle performance was also improved significantly.
Amorphous alloy Mg1.8Cu0.2Ni was successfully prepared by mechanical alloying (MA) and a series of (n-x)Ni-x(Ti+B) composites were synthesized by MA. The electrochemical properties of Mg1.8Cu0.2Ni coated by Ni, Ti and B were studied by cyclic charge-discharge, linear polarization curve, and hydrogen diffusion coefficient experiments. Experimental results indicate that Mg1.8Cu0.2Ni-[0.9Ni0.6(Ti+B)] composite which was MA 30 h exhibited the best performance and its initial discharge capacity arrived to 714.1 mAh/g. After 30 cycles the discharge capacity was above 530 mAh/g, which was much higher than that of Mg1.8Cu0.2Ni. And after 100 cycles it holded still 442.1 mAh/g. On all accounts, after modification by Ni, Ti and B, the initial discharge capacity and high-rate discharge ability of the electrode were evidently increased. At the same time, the cycle performance was also improved significantly.
