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SYNTHESIS AND PROPERTIES OF UV-CURABLE POLYSILOXANE METHACRYLATE OBTAINED BY ONE-STEP METHOD 被引量:4

SYNTHESIS AND PROPERTIES OF UV-CURABLE POLYSILOXANE METHACRYLATE OBTAINED BY ONE-STEP METHOD
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摘要 In this study, a UV-curable polysiloxane methacrylate (PSMA) was synthesized by a one-step method. The reaction was catalyzed by chloroplatinic acid between polymethylhydrosiloxane (PMHS) and hydroxyethyl methacrylate (HEMA), as proved by FTIR and ^1H-NMR. The preliminary results indicate that the obtained UV-cured PSMA film has very good thermal stability, excellent transparency and satisfactory tensile strength. Our work provides a simple but efficient way to prepare UV-curable PSMA, which may find potential applications in UV-curing optical fiber, metal and glass coating and other fields. In this study, a UV-curable polysiloxane methacrylate (PSMA) was synthesized by a one-step method. The reaction was catalyzed by chloroplatinic acid between polymethylhydrosiloxane (PMHS) and hydroxyethyl methacrylate (HEMA), as proved by FTIR and ^1H-NMR. The preliminary results indicate that the obtained UV-cured PSMA film has very good thermal stability, excellent transparency and satisfactory tensile strength. Our work provides a simple but efficient way to prepare UV-curable PSMA, which may find potential applications in UV-curing optical fiber, metal and glass coating and other fields.
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2013年第2期363-370,共8页 高分子科学(英文版)
关键词 Polysiloxane methacrylate UV-CURING Synthesis. Polysiloxane methacrylate UV-curing Synthesis.
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  • 1Chakraborty;R;Soucek;M.D.查看详情[J],Journal of Applied Polymer Science2010358.
  • 2(O)zgümüs;S;Iyim;T.B;Acar;I;Kücüko(g)lu;E.查看详情[J],Polymers For Advanced Technologies2007213.
  • 3Sun;F;Jiang;S.J;Du;H.G.查看详情[J],Journal of Applied Polymer Science20082994.
  • 4Thavomyutikam;B;Janvikul;W.查看详情[J],Macromolecular Symposium2008144.
  • 5Hou;S.S;Kuo;P.L.查看详情[J],Macromolecular Chemistry and Physics19992501.
  • 6Qi;Y.S;Meng;X;Yang;J.W;Zeng;Z.H.and Chen;Y.L.查看详情[J],Journal of Applied Polymer Science2005846.
  • 7Tang;C;Liu;W.Q.查看详情[J],J Coat Technol Res2010(05):651.
  • 8Cheng;X.E;Shi;W.F.查看详情[J],Progress in Organic Coatings2007312.
  • 9Liu;H.B;Chen;M.C;Huang;Z.T;Xu;K.;Zhang;X.J.;Chen;X.E.and Shi;W.F.查看详情[J],European Polymer Journal2004609.
  • 10Sun.F;Liao;L;Du;H.G;Huang;Y.D.查看详情[J],Journal of Applied Polymer Science20113604.

同被引文献28

  • 1Wei.Novel organometallic aromatic polyester based on ferrocene[J].Chinese Chemical Letters,2010,21(6):748-752. 被引量:2
  • 2LI Wenwen KONG Hao GAO Chao YAN Deyue.pH-responsive poly(2-diethylaminoethyl methacrylate)-functionalized multiwalled carbon nanotubes[J].Chinese Science Bulletin,2005,50(20):2276-2280. 被引量:3
  • 3高富堂,张晓镭,冯见艳,王兆闫.羟基硅油改性丙烯酸树脂的合成及其性能[J].应用化学,2006,23(7):790-793. 被引量:8
  • 4罗英武,许华君,李宝芳.细乳液聚合制备有机硅/丙烯酸酯乳液及其性能[J].化工学报,2006,57(12):2981-2986. 被引量:21
  • 5来国桥,幸松民.有机硅产品合成工艺及应用[M].北京:化学工业出版社,2009:11.
  • 6YAN Ping, QIU Liying. Preparation and characterization of polysiloxane-acrylate latexes with MPS-PDMS oligomer as macromonomer [ J].Journal of Applied Polymer Science, 2009, 114(2) : 760 -768.
  • 7MA Jianzhong, HU Jing, ZHANG Zhijie. Polyaerylate/ silica nanocomposite materials prepared by sol-gel process [ J ]. European Polymer Journal, 2007, 43(10) : 4169 -4177.
  • 8YILGOR Emel, YILGOR Iskende. Silicone containing copoIymers: synthesis, properties and applications [ J ]. Progress in Polymer Science, 2014, 39 (6) : 1165 - 195.
  • 9KELLER Michael Wade, WHITE Scott Ray, SOTTOS Nancy R. A self-healing poly ( dimethylsiloxane ) elastomer [ J]. Advanced Functional Materials, 2007, 17(14) : 2399 - 2404.
  • 10PEINADO Carmen, ALOSO Asuncion, CATALINA Fernando, et al. Using linear and branched polysilanes for the photoinitiated polymerization of a commercial silicone-acrylate resin, a real time FTIR study [ J ]. Journal of Photochemistry and Photobiology A: Chemistry, 2001 , 141 (1) : 85 -91.

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