摘要
根据燃烧理论和邻氯代苯亚甲基丙二腈(CS)刺激性控暴剂的化学结构,分析了焚烧法销毁CS刺激性控暴剂的反应原理和影响焚烧效果的主要因素,确定了CS完全燃烧的反应产物与反应方程式。通过焚烧试验研究了第一燃烧室和第二燃烧室温度、单次进料量、进料间隔时间对CS焚烧销毁效果的影响,据此优化确定了焚烧销毁废旧CS刺激性控暴剂的作业参数。结果表明,在过剩空气系数为2.0,单次进料量400 g,第一燃烧室温度750℃、第二燃烧室温度1100℃,进料间隔时间3 min的条件下利用试验设备能够有效地焚烧销毁CS控暴剂。
According to combustion theory and chemical structure of o-chlorobenzylidene malononitrile（CS）,the principle for destroying CS by Incineration was analyzed,and the reaction products and equation of the incineration were determined. By incineration experiments,the major influencing factors on the incineration effect,such as single feed-in waste quantity,feed-in time interval ,temperatures of the first and second firebox were discussed. Moreover,the optimized parameters for destroying CS by incineration equipment were deter- mined. As a result,CS can be thoroughly destroyed by the special incineration equipment under the optimized parameters that the excess air coefficient is 2.0,the feed-in waste quantity is 400 g each time,the feed-in time interval is 3 min ,the temperature of the first firebox is 750℃ and the second firebox is 1100℃.
出处
《含能材料》
EI
CAS
CSCD
北大核心
2013年第1期103-107,共5页
Chinese Journal of Energetic Materials
基金
国防基础预研基金(FHA26010109JX01)资助项目
关键词
应用化学
危险化学品
控暴剂
邻氯代苯亚甲基丙二腈(CS)
焚烧
销毁
applied chemistry
dangerous chemical
lacrimatory agent
o-chlorobenzylidene malononitrile（CS）
incineration destroying
