摘要
德国小蠊是世界上最难治理的卫生害虫之一.昆虫性信息素可作为一种安全有效的引诱剂用于害虫的综合治理.德国小蠊性信息素(blattellaquinone)因其结构不稳定而妨碍了它的实际应用.为了发现结构新颖且稳定的性信息素类似物,对blattellaquinone的结构中苯醌(A)、酯基(B)和脂肪链(C)部分进行了改造,设计并合成了一系列类似物,结构均通过1H NMR,IR和HRMS分析确证.
As one of the most important sanitation pests worldwide, German cockroach (Blattella germanica L.) is difficult to control. Insect sex pheromones are safe and efficient attractants used in integrated pest management. The sex pheromone of German cockroach had been identified as blatteUaquinone. The instability hampered the application of this compound. In order to find new and stable structures, a number of analogues were designed and synthesized by modification of the quinone ring (A), aliphatic terminal (B) and ester group (C) of blattellaquinone. The structures were confirmed by 1H NMR, IR spectra and HRMS analysis.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2013年第1期178-183,共6页
Chinese Journal of Organic Chemistry
关键词
德国小蠊
小蠊醌
性信息素类似物
合成
Blattella germanica
blattellaquinone
sex pheromone analogues
synthesis