期刊文献+

H_2O_2氧化苯制苯酚反应体系的分析方法

Analysis Method for the Oxidation of Benzene to Phenol by Hydrogen Peroxide
在线阅读 下载PDF
导出
摘要 采用气相色谱对双氧水氧化苯制苯酚反应体系中苯、苯酚的含量进行测定。给出了含量测定的具体方法。由于同一检测器对不同物质具有不同的响应值,采用校正面积归一法。以苯为参考峰,测得苯酚的相对校正因子为1.4625。同时,给出了反应过程中苯转换率及苯酚选择性的计算方法。 The fraction of benzene and phenol in the direct oxidation of benzene using hydrogen peroxide was determined by GC. Because of the different response value between benzene and phenol, the method of correction area was used. With benzene as the reference, relative correction factor of phenol was 1. 4625. The methods of calculating the turn- over of benzene and the selectivity of phenol were also elaborated.
作者 石荣荣
出处 《广州化工》 CAS 2013年第1期118-120,共3页 GuangZhou Chemical Industry
关键词 双氧水 苯酚 分析方法 benzene hydrogen peroxide phenol analysis
  • 相关文献

参考文献3

二级参考文献14

  • 1臧开保.邻苯二酚合成新工艺研究[J].农药,1993,32(3):22-24. 被引量:8
  • 2Michel C , Dominique L . Process for hydroxylating phenols and phenol ethers [P]. EP,432 006. 1991 -06 - 12.
  • 3Sumio U, Nagaaki T, Toshikazu H, et al. Process for preparing dihydric phenol derivatives [P]. US,4 078 006. 1976 - 04 - 30.
  • 4Michel C , Adrien D , Michel J . Process for hydroxylating phenolic compounds[P]. EP,480 800.1990 - 10 - 8.
  • 5Taramasso M , Perego G , Notari B. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides[P]. US,4 410 501. 1983 -10 - 18.
  • 6Tuel A, Moussa - Khouzami S, Ben Taarit Y, et al.Hydroxylation of phenol over TS- 1: surface and solvent effects[J]. J Mol Catal, 1991,68: 45 - 52.
  • 7Thangaraj A, Puthoor L , Sivasanker S. Solvent effeets in the hydroxylation of phenol with H202 over TS - 1[J]. Indian J Chem Sect A, 1994,33(3) : 255 -258.
  • 8Marco Taramasso, Giovanni Perego, Bruno Notari. Preparation of porous crystalline synthetic material comprised of titanium oxides[P]. US:4 410 501, 1983-10-18.
  • 9Chul Wee Lee, Dong Hwan Ahn, Bo Wang et al. Hydroxylation of phenol over surface functionalized MCM-41 supported metal catalyst[J]. Microporous and Mesoporous Materials, 2001, 44-45:587-594.
  • 10Dubey A, Rives V, Kannan S. Catalytic hydroxylation of phenol over ternary hydrotalcites containing Cu, Ni and Al[J]. J Mol Catal A: Chem, 2002,181(1-2):151-160.

共引文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部