摘要
采用高温熔融法制备了3种带有四羧基的单核金属酞菁配合物,通过红外光谱、紫外-可见光谱、热重分析等对产物进行表征。结果表明,ZnPc(COOH)4、CuPc(COOH)4、FePc(COOH)4在紫外-可见光区域的最大吸收波长分别为645、641、632nm,其热稳定性优劣顺序为FePc(COOH)4>ZnPc(COOH)4>CuPc-(COOH)4。
High-temperature melting method was employed to prepare FePc（COOH）4,CuPc-（COOH）4,and ZnPc（COOH）4,which were then characterized by IR,UV,and TG.The results show that the largest UV-VIS spectra absorption wavelengths of FePc（COOH）4,CuPc（COOH）4 and ZnPc（COOH）4 are 645,641,and 632 nm,respectively.The thermostability of the three products follows the order of FePc（COOH）4ZnPc（COOH）4 CuPc（COOH）4.
出处
《武汉科技大学学报》
CAS
2013年第1期55-58,共4页
Journal of Wuhan University of Science and Technology
关键词
金属酞菁配合物
单核
光谱吸收
热稳定性
metal phthalocyanine complexes
mononuclear
spectral absorption
thermostability
