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Laser-induced Fluorescence Spectroscopy of NiCl in 12900-15000 cm-1

Laser-induced Fluorescence Spectroscopy of NiCl in 12900-15000 cm-1
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摘要 Laser-induced fluorescence excitation spectra of jet-cooled NiC1 molecules were recorded in the energy range of 12900-15000 cm-1. Six vibronic bands with rotational structure have been observed and assigned to the [13.0]2II3/2(v'=0-5)-X2II3/2(v"=0) transition progression. The relevant rotational constants, significant isotopic shifts, and (equilibrium) molecular parameters have been determined. In addition, the lifetimes of the observed bands have also been measured.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第6期631-635,I0003,共6页 化学物理学报(英文)
基金 This work was supported by the National Natural Science Foundation of China (No.21273212, No.20873133, and No.21173205), the National Key Basic Research Program of China (No.2010CB923302), the Chinese Academy of Sciences (No.KJCX2-YW-N24), the FRFCUC (No.WK2340000012), and the USTC-NSRL Joint Funds (No.KY2340000021).
关键词 NiC1 Laser-induced fluorescence Isotopic shift 激光诱导荧光光谱 荧光激发光谱 分子参数 同位素位移 射流冷却 能量范围 转动结构 转动常数
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