摘要
综述了微波辅助原子转移自由基聚合(ATRP)反应在高分子的本体、溶液及合成功能性高分子中的应用进展。分析微波对原子转移自由基聚合反应转化率、表观速率常数、相对分子质量及其分布、聚合物结构和性能的影响,指出微波可大大降低聚合反应时间与能耗。并对微波加热在原子转移自由基聚合反应的研究工作提出建议和展望。
The development of microwave assisted atom transfer radical polymerization （ATRP） used in bulk polymerization, solution polymerization and the synthesis of functional polymers were reviewed. The im pacts of microwave radiation in ATRP on conversion, apparent constant, molecular weight and distribution, polymer structure and performance were examined . It was pointed out that the microwave could greatly de crease the polymerization time and energy consumption, Suggestions on the application of microwave heating in ATRP were also given.
出处
《精细石油化工进展》
CAS
2012年第11期32-35,39,共5页
Advances in Fine Petrochemicals
基金
黑龙江省自然科学基金重点项目(ZJG0507)
关键词
微波原子转移自由基
聚合
聚合物
microwave
atom transfer radical polymerization
polymer
