期刊文献+

食用油中3-氯-1,2-丙二醇酯检测方法的研究进展 被引量:7

Research Progress on the Determination of 3-Monochlorpropane-1,2-Diol Esters in Edible Oil
在线阅读 下载PDF
导出
摘要 3-氯-1,2-丙二醇酯(3-MCPD酯)是油脂精炼过程中引入的又一潜在危害因子,它是3-氯丙醇与脂肪酸的酯化产物。目前3-MCPD酯测定方法的研究已成为当今食品安全检测的一大热点。本文综述了近几年来国内外食用油中3-MCPD酯的检测方法,包括酸催化酯交换间接测定法、碱催化酯交换间接测定法以及直接测定法,详细介绍了各种检测方法的研究现状及优缺点,并讨论了未来3-MCPD酯检测技术的研究发展方向,为今后我国建立食用油中3-MCPD酯标准分析方法提供参考和依据。 3 -monochloropropane- 1,2 -diol(3 -MCPD)esters are potential contaminants produced in oil re- fining process. They are the esterification products between 3 - MCPD and fatty acids. Now, analysis of 3 - MCPD es- ters has attracts wide research interest in food safety. This article reviewed the determination methods of 3 - MCPD es- ters in edible oil in our country, including the indirect methods (acid transesterification and base transesterification) and the direct method. The current situation and advantages and disadvantages of these methods were further dis- cussed. And the research and development orientation for the determination technology of 3 - MCPD esters in the fu- ture had also been discussed. This review may provide useful information for establishing the standard for determina- tion of 3 -MCPD esters in edible oil in our country.
出处 《中国粮油学报》 EI CAS CSCD 北大核心 2012年第12期122-128,共7页 Journal of the Chinese Cereals and Oils Association
关键词 食用油 3-氯丙醇酯 检测 edible oil ,3 - monochlorpropane - 1,2 - diol esters, determination
  • 相关文献

参考文献23

  • 1杨娇,金青哲.食用植物油中3-氯丙醇酯的研究进展[J].中国油脂,2011,36(9):1-4. 被引量:32
  • 2Seefelder W, Varga N, Studer A, et al. Esters of 3 - chloro - 1,2 - propanediol ( 3 - MCPD ) in vegetable oils : significance in the formation of 3 -MCPD[ J]. Food additives & contami- nants. Part A, Chemistry, analysis, control, exposure & risk as- sessmen ,2008,25 (4) : 391 - 400.
  • 3Koning S, Zelinkovd Z, Hrncirik K, et al. Analysis of 3 - MCPD esters in edible oils using large volume injection cou- pled to comprehensive gas ehromatography - time -of- flight mass spectrometry[ EB/OL]. http://www, atasgl, eom/ ap - note/112 - PEG4D - 3 - MCPD - ESTERS - IN - EDI- BLE - OILS. pdf.
  • 4Weisshaar R. Fatty acid esters of 3 - MCPD : overview of oc- currence and exposure estimates [ J ]. European Journal of Lipid Science and Technology,2011,113:304 - 308.
  • 5Weisshaar R. Determination of total 3 - chloropropane - 1, 2 -diol in edible oils by GC - MS after ester cleavage with sodium methoxide [ J ]. European Journal of Lipid Science and Technology,2008,110 : 183 - 186.
  • 6Weif~haar R, Perz R. Fatty acid esters of glycidol in refined fats and oils [ J ]. European Journal of Lipid Science and Technology ,2010,112 : 158 - 165.
  • 7Karasek L, Wenzl T, Ulberth F. Determination of 3 - MCPD esters in edible oil - methods of analysis and comparability of results[ J ]. European Journal of Lipid Science and Technolo- gy, 2011,113 : 1433 - 1442.
  • 8C -III 18 (09) Ester - bond 3 - chloropropane - 1,2 - diol ( 3 - MCPD - esters ) and glycidou( glycidyl esters ) [ S ]. DFG Standard Method Section C - Fats.
  • 9Kaze N, Sato H, Yamamoto H, et al. Improvement of accuracy in quantification of 3 - monochloropropane - 1,2 - diol esters by Deutsche Gesellschaft fu"r Fettwissenschaft standard meth- ods C- III 18 [J]. European Journal of Lipid Science and Technology,2011,113:1168 - 1171.
  • 10王力清,陈洪涛,廖继承,刘嘉亮,郦明浩,杨天奎.同位素稀释GC-MS/MS方法测定油脂中3-MCPD脂肪酸酯和缩水甘油脂肪酸酯的总量[J].农业机械,2011(16):61-63. 被引量:14

二级参考文献23

  • 1柳洁,何碧英,孙俊红.氘代同位素内标GC/MS法测定食品中3-氯-1,2-丙二醇的方法研究[J].中国卫生检验杂志,2005,15(4):392-395. 被引量:5
  • 2HAMLET C G, SADD P A, CREST C, et al. Occurrence of 3 - chloro - propane - 1,2 - diol (3 - MCPD) and relat- ed compounds in foods: a review[ J ]. Food Additives and Contaminants,2002, 19:619 - 631.
  • 3SVEJKOVSKA B, NOVOTNY O, DIVINOVA V, et al. Esters of 3 - chloropropane - 1,2 - diol in foodstuffs [ J ]. Czech J Food Sci,2004, 22 : 190 - 196.
  • 4ZELINKOVA Z, SVEJKOVSKA B, VELISEK J, et al. Fat- ty acid esters of 3 - chloropropane - 1,2 - diol in edible oils [ J ]. Food Additives and Contminants, 2006, 23 : 1290 - 1298.
  • 5YAYLAYAN V A. Molecular mechanism of 3 -MPCD es- ter formation: facts and hypothesis [ R ]. Belgium: ILSI Workshop on 3 - MCPD esters,2009.
  • 6RAHN A K K, YAYLAYAN V A. What do we know about the molecular mechanism of 3 - MCPD ester formation? [ J ]. Eur J Lipid Sci Technol, 2011, 113:323 - 329.
  • 7LARSEN J C. 3 - MCPD esters in food products [ M ]. Brussels: ILSI Europe a. i. s. b. 1,2009:1 -25.
  • 8PUDEL F, BENECKE P, FEHLING P, et al. On the ne- cessity of edible oil refining and possible sources of 3 - MCPD and glycidyl esters [ J ]. European Journal of Lipid Science and Technology,201 I, 113 (3) :368 - 373.
  • 9HAMLET C G, ASUNCION L. Single- laboratory valida- tion of a method to quantify bound 2 - chloropropane - 1, 3 - diol and 3 - chloropropane - 1,2 - diol in foodstuffs using acid catalysed transesterification, HFBI derivatisation and GC/MS detection[ J]. European Journal of Lipid Sci- ence and Technology,2011,113:345 - 355.
  • 10HAMLET C G, ASUNCION L, VELISEK J, et al. Forma- tion and occurrence of esters of 3 - chloropropane - 1, 2 - diol (3 - CPD) in foods : what we know and what we assume[ J]. European Journal of Lipid Science and Tech- nology,2011,113 : 279 - 303.

共引文献41

同被引文献47

  • 1王卫华,徐锐锋,刘军,薛静,刘俊会.食品中氯丙醇测定方法研究进展[J].化学分析计量,2007,16(3):74-76. 被引量:9
  • 2ZELINKOV. Z, SVEJKOVSK B, VEIEK J, et al. Fatty acid esters of 3 -chloropropane- 1,2- diol in edible oils [J]. Food Addit Contam, 2006, 23(12): 1290-1298.
  • 3HAMLET C G, SADD P A, CREWS C, et al. Occurrence of 3 - chloro - propane - 1,2 - diol (3 - MCPD) and relat- ed compounds in foods: a review [ J ]. Food Addit Cont- am, 2002, 19(7): 619-631.
  • 4WEISSHAAR R. 3 -MCPD- esters in edible fats and oils--a new and worldwide problem [ J ]. Eur J Lipid Sci Technol, 2008, 110(8) : 671 -672.
  • 5FRANKE K, STRIJOWSKI U, FLECK G, et al. Influence of chemical refining process and oil type on bound 3 - chlo- ro - 1,2 - propanediol contents in palm oil and rapeseed oil [J]. Food Sci Teehnol, 2009, 42(10) : 1751 -1754.
  • 6MASSEY R, HAMLET C. Chloropropanol contaminants in food:the story continues [ J]. Food Sci Teeh, 2007, 21 (4) : 32 -34.
  • 7WEIBHAAR R. Fatty acid esters of 3 - MCPD : overview of occurrence in different types of foods [ EB/OL ]. [ 2015 - 04 - 10 ]. http ://www. cvua - stuttgart, de.
  • 8MYHER J J, KUKSIS A, MARAI L, et al. Stereospecific analysis of fatty acid esters of chloropropanediol isolated from fresh goat milk [ J]. Lipids, 1986, 21 (5): 309 - 314.
  • 9HAMLET C G, SADD P A, GRAY D A. Generation of monochloropropanediols (MCPDs) in model dough sys- tems. 1. Leavened doughs [J]. J Agric Food Chem, 2004, 52 (7) : 2059 - 2066.
  • 10LYNCH B S, BRYANT D W, HOOK G J, et al. Carcinoge- nicity of monochloro - 1, 2 - propanediol ( α - chlorohydrin, 3 - MCPD) [ J ]. Int J Toxicol, 1998, 17 ( 1 ) : 47 - 76.

引证文献7

二级引证文献83

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部