摘要
Monte Carlo simulation is applied, with a high effectiveness and versatility, to the studies on the kinetics and chain length distribution in radical polymerization with RAFT process. The results show that the molecular weight the resulting polymers increase linearly with monomer conversion, and the polydispersity is lower than 1.1, a typical feature of living polymerization. The simulation results are in consistent with the experimental results in literature. Additionally, that the molecular weight is proportional to the initial concentration of dithioester, [DSE]0, and the polymerization rate is [DSE]0-independent, could be of great help for controlling molecular weight in experiment.
Monte Carlo simulation is applied, with a high effectiveness and versatility, to the studies on the kinetics and chain length distribution in radical polymerization with RAFT process. The results show that the molecular weight the resulting polymers increase linearly with monomer conversion, and the polydispersity is lower than 1.1, a typical feature of living polymerization. The simulation results are in consistent with the experimental results in literature. Additionally, that the molecular weight is proportional to the initial concentration of dithioester, [DSE]_0, and the polymerization rate is [DSE]_0-independent, could be of great help for controlling molecular weight in experiment.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2000年第7期1146-1148,共3页
Chemical Journal of Chinese Universities
基金
国家重点基础研究专项经费! (批准号 :G19990 648)
国家自然科学基金
教育部优秀青年教师基金
