摘要
邻甲苯酚与丙烯腈经Friedel-Crafts反应得到了2-甲基-4-β-氰基乙基苯酚,其与1-氨基-2-溴-4-羟基蒽醌经亲核取代形成的产物经水解、酯化得到目标化合物。给出了该化合物及其中间体的质谱、核磁共振氢谱、元素分析、可见光谱及熔点等数据。
2 - Methyl - 4 - B - cyanoethylphenol was synthesized via Friedel - Crafts reaction between o - cresol and acrylonitrile. It was condensed with 1 - amino - 2 - bromo - 4 - hydroxy anthraquinone by the nucleophilic reaction. The product was hydrolyzed in alkaline medium and esterified with methanol to afford the title compound . Mass , H NMR, element analyses, Vis spectra and the melting points of the title compound and the intermediates were measured .
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2000年第4期533-536,共4页
Chinese Journal of Organic Chemistry
关键词
邻甲苯酚
丙烯腈
蒽酯
合成
染料
2 - methyl - 4 -β - cyanoethylphenol, 1 - amino - 2 - ( 2' - methyl - 4' - methylpropionate) phe-noxy - 4 - hydroxy anthraquinone, synthesis
