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卟啉降冰片烯聚合物的合成、表征及性质研究

Syntheses,Characterization and Property Studies on Porphyrinic Polynorbornenes
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摘要 本文设计合成了卟啉的降冰片烯单体,采用Grubbs催化剂与长链烷基的降冰片烯单体开环易位聚合,直接得到了卟啉降冰片烯聚合物,通过紫外-可见吸收光谱、荧光光谱、电化学等手段研究了卟啉降冰片烯聚合物的性质,与小分子单体相比,所得卟啉高分子共聚物相当好地保持了卟啉应有的光物理、电化学等特性. Porphyrinic and long-chain alkyl norbornene monomers have been designed and synthesized,and copolymers were obtained via ROMP（ring-opening metathesis polymerization） using a Grubbs′ initiator.The properties of porphyrinic polynorbornenes have been investigated by UV-Vis absorption spectroscopy,steady-state fluorescence spectroscopy,lifetime measurements and electrochemistry.The copolymers exhibit almost identical characteristics as well as porphyrinic monomers in photophysics and electrochemistry.
作者 李辉 冯科 周力 陈彬 张丽萍 佟振合 吴骊珠
机构地区 南昌大学化学系 中国科学院理化技术研究所光化学转换与功能材料重点实验室
出处 《影像科学与光化学》 CAS CSCD 北大核心 2012年第6期429-437,共9页 Imaging Science and Photochemistry
基金 科技部国家重点基础研究发展规划项目(2009CB220008 2013CB8343505) 国家自然科学基金资助项目(21002108 91027041 20973189 21090343 50973125) 中国科学院知识创新工程太阳能行动计划资助项目
关键词 卟啉 降冰片烯聚合物 开环易位聚合 porphyrin polynorbornenes ring-opening metathesis polymerization
分类号 O631.5 [理学—高分子化学]
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影像科学与光化学
2012年 第6期

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