摘要
A metal-organic coordination polymer [Ni（PDB）（bix）（H20）]n （H2PDB = 3,4-pyri- dinedicarboxylic acid, bix = 1,4-bis（imidazol-l-ylmethyl）-benzene） 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. Blue crystals crystallize in the triclinic system, space group PI with a = 9.1849（8）, b = 9.2065（9）, c = 12.9308（12） °, a = 103.3070（10）, β = 104.7160（10）, y = 90.5900（10）°, V = 1026.42（16）/k3, C21H19NsNiOs, Mr = 480.12, Dc = 1.553 g/cm3, F（000） = 496, Z = 2,/l（MoKa） = 0.991 mm-1, the final R = 0.0325 and wR = 0.0799 for 3561 observed reflections （I 〉 2σ（I））. The structure of 1 exhibits a two-dimensional network structure.
A metal-organic coordination polymer [Ni（PDB）（bix）（H20）]n （H2PDB = 3,4-pyri- dinedicarboxylic acid, bix = 1,4-bis（imidazol-l-ylmethyl）-benzene） 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. Blue crystals crystallize in the triclinic system, space group PI with a = 9.1849（8）, b = 9.2065（9）, c = 12.9308（12） °, a = 103.3070（10）, β = 104.7160（10）, y = 90.5900（10）°, V = 1026.42（16）/k3, C21H19NsNiOs, Mr = 480.12, Dc = 1.553 g/cm3, F（000） = 496, Z = 2,/l（MoKa） = 0.991 mm-1, the final R = 0.0325 and wR = 0.0799 for 3561 observed reflections （I 〉 2σ（I））. The structure of 1 exhibits a two-dimensional network structure.
基金
supported by the Science and Technology Development Project of Jilin Provincial Science & Technology Department(201205080)
