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Synthesis, Crystal Structure and Magnetic Properties of a Sandwich-type Polyoxometalate [H_2N(CH_2CH_2)_2O]_10[Mn_2(As^VMo_9O_(33))_ 2 ]·12H_2O

Synthesis, Crystal Structure and Magnetic Properties of a Sandwich-type Polyoxometalate [H_2N(CH_2CH_2)_2O]_10[Mn_2(As^VMo_9O_(33))_ 2 ]·12H_2O
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摘要 A new heteropolymolybdoarsenate [H2N（CH2CH2）20]lo[Mn2（AsVM09033）2].12H2O （1） has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. The crystal is made up of sandwich-type [Mn2（AsVM09033）2]10- anions, [H2N（CH2CH2）20]＊ cations and H20 molecules of crystallization. The magnetic properties of 1 have been studied by measuring its magnetic susceptibility in the temperature range of 2.0-300.0 K, indicating the existence of antiferromagnetic interactions. A new heteropolymolybdoarsenate [H2N（CH2CH2）20]lo[Mn2（AsVM09033）2].12H2O （1） has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. The crystal is made up of sandwich-type [Mn2（AsVM09033）2]10- anions, [H2N（CH2CH2）20]＊ cations and H20 molecules of crystallization. The magnetic properties of 1 have been studied by measuring its magnetic susceptibility in the temperature range of 2.0-300.0 K, indicating the existence of antiferromagnetic interactions.
作者 杨艳艳 许林 曲小姝 娄大伟
机构地区 Jilin Institute of Chemical Technology Institute of Polyoxometalates
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第11期1539-1544,共6页 结构化学（英文）
基金 supported by the Science and Technology Development Foundation of Jilin Province(201201105)
关键词 heteropolymolybdoarsenate MANGANESE crystal structure heteropolymolybdoarsenate, manganese, crystal structure
分类号 O611.3 [理学—无机化学]
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Chinese Journal of Structural Chemistry
2012年 第11期

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