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Study on the Effect of Underground Temperature on the Adsorption Behavior of Chlorobenzene under Artificial Recharge Condition 被引量:1

Study on the Effect of Underground Temperature on the Adsorption Behavior of Chlorobenzene under Artificial Recharge Condition
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摘要 [ Objective] The research aimed to study the effect of underground temperature on the adsorption behavior of chlorobenzene under artifi- cial recharge condition. [ Method] Based on the prior researches, combining actual condition of the artificial recharge test site, the adsorption be- havior of chlorobenzene under the background of artificial recharge was discussed. [ Reset ] The adsorption reaction of chlorobenzene correspon- ded with quasi-first-order and quasi-second-order kinetics equations at certain concentration. When temperature rose, reaction rate accelerated, and adsorption balance time shortened to 12 (0 ℃), 10 (10 ℃) and 8 (20 ℃) h. The adsorption of chlorobenzene corresponded with isothermal adsorption model very well at different concentrations. When temperature ranged from 0 to 20 ℃, the adsorption amount of medium on chloroben- zene increased at equilibrium time. The maximal adsorption amounts calculated by Langmuir model were 20.747, 21. 505, 23.364 μg/g at 0, 10 and 20 ℃, respectively. [ Conclusion] The adsorption of chlorobenzene in aquifer medium was endothermic reaction, and the best season of artifi- cial recharne was in summer. [ Objective] The research aimed to study the effect of underground temperature on the adsorption behavior of chlorobenzene under artifi- cial recharge condition. [ Method] Based on the prior researches, combining actual condition of the artificial recharge test site, the adsorption be- havior of chlorobenzene under the background of artificial recharge was discussed. [ Reset ] The adsorption reaction of chlorobenzene correspon- ded with quasi-first-order and quasi-second-order kinetics equations at certain concentration. When temperature rose, reaction rate accelerated, and adsorption balance time shortened to 12 (0 ℃), 10 (10 ℃) and 8 (20 ℃) h. The adsorption of chlorobenzene corresponded with isothermal adsorption model very well at different concentrations. When temperature ranged from 0 to 20 ℃, the adsorption amount of medium on chloroben- zene increased at equilibrium time. The maximal adsorption amounts calculated by Langmuir model were 20.747, 21. 505, 23.364 μg/g at 0, 10 and 20 ℃, respectively. [ Conclusion] The adsorption of chlorobenzene in aquifer medium was endothermic reaction, and the best season of artifi- cial recharne was in summer.
出处 《Meteorological and Environmental Research》 2012年第8期63-66,71,共5页 气象与环境研究(英文版)
基金 Supported by National Natural Science Foundation Project, China (41103045) "Science Frontier and Interdiscipline Innovation Project" ,Jilin University, China (201003031)
关键词 CHLOROBENZENE ADSORPTION Artificial recharge GROUNDWATER China Chlorobenzene Adsorption Artificial recharge Groundwater China
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  • 1杨学耀,李进,李久义,李强.好氧颗粒污泥吸附重金属Cd(Ⅱ)的研究[J].工业用水与废水,2007,38(1):28-31. 被引量:10
  • 2陈雪松,夏四清,刘贵春.SBR好氧颗粒污泥的理化性质研究[J].中国给水排水,2007,23(9):99-102. 被引量:18
  • 3刘祖洞.遗传学[M].北京:高等教育出版社,2002.
  • 4VERHAAR H J, VE1TH G D. Classifying environmental pollutants( Ⅰ )structure-activity relationships for prediction of aquatic toxicity [J]. Chemosphere, 1992, 25,471.
  • 5刘文君,张丽萍.城镇供水应急技术手册[M].北京:中国建筑工业出版社,2007:111-112.
  • 6SING K S W, EVERETT D H, HAUL R A W, et al. Reporting physisorption data for gas/solid systems, with special reference to the determination of surface area and porosity [ J]. Pure and Applied Chemistry, 1985, 57: 603 -619.
  • 7JUANG R S, WU F C, TSENG R L. Mechanism of adsorption of dyes and phenols from water using activated carbons prepared from plum kernels [ J ]. Journal of Colloid and Interface Science, 2000, 227:437 -444.
  • 8PELEKANI C, SNOEYINK V L. Competitive adsorption in natural water: Role of activated carbon pore size [ J]. War Res, 1999, 33(5) :1209 -1219.
  • 9PELEKANI C, SNOEYINK V L. Competitive adsorption between atrazine and methylene blue on activated carbon: The importance of pore size distribution [ J]. Carbon, 2000,38 : 1423 - 1436.
  • 10MCNAUGHT A D, WILKINSON A. Compendium of Chemical Terminology : IUPAC Recommendations [ M ]. 2nd ed. Blackwell Science: Malden, MA, 1997.

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  • 1GOLUBINA EV, LATEVS ES, LUNIN W, et al. The role of Fe addition on the activity of Pel-containing catalysts in multiphase hydrodechlorination[J]. Applied Catalysis A: General, am, :n2(1): 32 -41.
  • 2HAN Y, LI W, ZHANG M, et al. catalytic dechlorination of monochlorobenzene with a new type of nanoscale Ni( B)/Fe( B) bimetallic catalytic reductant[J]. Chemosphere, 2008, 72(1): 53 -58.
  • 3JANIAK T. Kinetics of o-chlorotoluene hydrogenolysis in the presence of 3%,5% and 10% Pd/C catalysts[J]. Applied catalysis A: General, 2008, 335(1): 7 -14.
  • 4EVDOKIMOVA G, PEROSA A, ZINOVYEV S, et al. Selectivity issues in the catalytiC multiphase reduction of functionalized halogenated aromatics over Pd/C, PVC, and Raney-Ni [J]. Applied catalysis A: General, 2004, 271 (1/2): 129 -136.
  • 5XU X, ZHOU M, HE P, et al. catalytic reduction of chlorinated and recalcitrant compounds in contaminated water [J]. Journal of Hazardous Materials, 2005, 123(1/3): 89 -93.
  • 6ZHU BW, LIM TT, FENG J. Reductive dechlorination of 1,2,4-trichlorobenzene with palladized nanoscale FeO particles supported on chitosan and sillca[J]. Chemosphere, 2006, 65(7): 1137 -1145.
  • 7TUNDO P, PEROSA A, ZINOVYEV S. Modifier effects on PVC, Pd/C, and Raney-Ni catalysts in multiphase catalytic hydrogenation systems [J]. Journal of Molecular Catalysis A: Chemical, 2003, 204/205: 747 -754.
  • 8ZINOVYEV S, PEROSA A, YUFIT S, et al. Hydrodechlorination and hydrogenation over Raney-Ni under multiphase conditions: Role of multiphase environment in reaction kinetics and selectivity [J]. Journal of Catalysis, 2002, 211 (2): 347 -354.
  • 9ZINOVYEV S, SHELEPCHIKOV A, TUNOO P. Design of new systems for transfer hydrogenolysis of polychlorinated aromatics with 2- propanol using a Raney nickel catalyst [J]. Applied catalysis B: Environmental, 2007, 72(3/4): 289 -298.
  • 10ZlNOVYEV S, TUNDO P. On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst [J]. Applied catalysis B: Environmental, 2007, 75(1/2): 124-128.

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