功能化活性炭固载离子液体催化剂被引量：5

Catalyst of Ionic Liquid Immobilized on the Functionalized Activated Carbon

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摘要制备了活性炭固载溴化1-(2-胺乙基氢溴酸)-3-甲基咪唑鎓盐离子液体催化剂,并用TG和XPS对催化剂进行了表征。将该催化剂首次用于Knoevenagel缩合反应,结果表明活性炭固载离子液体催化剂具有良好的催化活性和稳定性,同时克服了均相催化剂难以分离的不足。 Ionic liquid/activated carbons （AC） catalysts have been prepared by a chemical method that involves functionalization of AC with 1-（2-amine ethyl hydrogen）-3-methylimidazoliurn bromide ionic liquids. It was used in Knoevenagel condensation reaction for the first time.The immobilized IL was then characterized by X-ray photoelectron spectroscopy and thermogravimetric analysis （TGA） spectra. Ionic liquid/activated carbon （AC） catalyst showed good catalytic performance toward Knoevenagel condensation reaction,and overcome the inseparable shortage of the homogeneous catalyst.

作者崔露丹马磊

机构地区浙江工业大学工业催化研究所

出处《浙江化工》 CAS 2012年第10期12-14,20,共4页 Zhejiang Chemical Industry

关键词离子液体活性炭固载催化剂 ionic liquid activated carbon immobilized catalyst

分类号 O643.36 [理学—物理化学]

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