摘要
制备了两种不同的含氮高分子-钯络合物，并研究了它们对对硝基甲苯的催化活性。结果发现，聚苯乙烯负载的苯乙烯-二乙烯基苯-马来酸酐交替共聚物与氨反应提到的高分子-钯络合物，在常温常压下对对硝基甲苯催化氢化有很高的活性，产物对甲苯胺的收率为100％。
Two different kinds of palladium complexes of nitrogen containing polymere havebeen prepared and their catalytic actions for p -nitro -methyl benzfene have been invertigeted. Ithas been found that the kind of palladium complexes of the polymer obtained by the reaction of PS -supported styrene - divinylstyrene - malelic anhydride alternating copolymer withammonia is highly active hydrogenation catalyst of p -nitromethylbenzene at room temperatureand atmospheric pressure, and p-methyl aniline can be obtained in 100% yield.
出处
《黑龙江商学院学报》
2000年第2期100-103,共4页
Journal of Harbin Commercial University(Natural Sciences Edition)
关键词
对硝基甲苯
对甲苯胺
催化剂
催化
氢化
Pd-complex of polymer
p-nitromethyl benzene
P-methyl aniline
