摘要
A naturally occurring nucleoside disulfide, 9-（51-deoxy-5t-thio-β-D-xylofuranosyl）adenine disulfide, was first synthesized from o-xylose over 7 steps in 20% overall yield. The key step involved Vorbri.iggen glycosylation of silylated N6-benzoyladenine with xylose diacetate moiety.
A naturally occurring nucleoside disulfide, 9-（51-deoxy-5t-thio-β-D-xylofuranosyl）adenine disulfide, was first synthesized from o-xylose over 7 steps in 20% overall yield. The key step involved Vorbri.iggen glycosylation of silylated N6-benzoyladenine with xylose diacetate moiety.
基金
NSFC(Nos.20962009 and 21062006)
NCET(No.11-1000)
the Training Project of Jiangxi Youth Scientists,Education Department of Jiangxi Province(No.GJJ 11223)
Bureau of Science & Technology of Nanchang City for financial support
