摘要
采用水热法合成了两个新颖的配合物{[Ni(H2qptc)(4,4′-bpy)(H2O)2].2(H2O)}n(1)和[Zn2(H2O)2(qptc)(4,4′-bpy)]n(2)(H4qptc:三联苯-2,5,2′,5′-四羧酸,4,4′-bpy:4,4′-联吡啶),并对其进行了元素分析、热重、红外光谱和、磁性和X-射线单晶衍射测定。化合物1和2都是三维结构,分别显示(65.8)-cds、(42.6)2(43.62.8)(45.64.8)2.拓扑结构。
Solvothermal reactions of aromatic terphenyl-2,5,2′,5′-tetracarboxylic acid（H4qptc） ligand and transitionalmetal cations of M Ⅱ（M=Ni,Zn） in the presence of 4,4′-bipyridine（4,4′-bpy） afford two new coordinationpolymers（CPs）,namely,{[Ni（H2qptc）（4,4′-bpy）（H2O）2].2（H2O）}n（1） and [Zn2（H2O）2（qptc）（4,4′-bpy）]n（2）.Theirstructures have been determined by single-crystal X-ray diffraction analyses and further characterized byelemental analyses,TGA,and magnetism.In 1,the H2qptc2-acts as a Z-shaped ligand linking the NiⅡ centers toa 1D zigzag polymeric [Ni（H2qptc）]n chain,based on which a unique 3D 4-connected framework with distorted（65.8）-cds topology is formed.For 2,the qptc4-acts as a H-shaped ligand linking the ZnⅡ centers together to forma 2D polymeric [Zn（qptc）]n layer,which is further connected by 4,4′-bpy,thus generating a 3D（3,4）-connectednetwork with the Schlfli symbol of （42.6）2（43.62.8）（45.64.8）2.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2012年第9期1809-1816,共8页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.21101097)
山东省自然科学基金(No.ZR2010BQ023)资助项目
