摘要
全氟或多氟烷基氯代烷在保险粉引发下在DMSO溶剂中可以与富电子芳香烃反应,方便地得到氟烷基化的产物.氟烷基化产物的结构和产率主要取决于取代基的供电子能力和位置.
Per (poly) fluoroalkyl chlorides could smoothly react with electron - rich aromatic compounds induced by sodium dithionite in DMSO to give the per ( poly) fluoroalkylated aromatics. The structures and yields of perfiuoroalkylated products depend mainly on the positions and electron - donating ability of the substituents.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
2000年第6期713-716,共4页
Acta Chimica Sinica
基金
国家自然科学基金(29772048)资助
