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钴(II)螯合物及其氧加合物质谱研究

Mass Spectroscope Studies of Cobalt(II) Base Compound and Its Oxygen Adduct
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摘要 用质谱测量方法对四齿配体席夫碱L1(L1=邻苯二胺缩-1-苯基-3-甲基-4-苯甲酸基吡唑啉酮-5)、CoL2(CoL2=乙二胺缩-1-苯基-3-甲基-4-苯甲酸基毗唑啉酮-5合钴(II)螯合物及其氧加合物(CoL2·Py·O2·2H2O)进行研究,与其它的分析、测定方法相结合,确定其组成和结构. One tetradentate Schiff base L_1 (L_1 =N, N' -O-phenylene bis (1 -phenyl-3 -methyl-4- Benzoyliminephrazolone - 5) and Col_2 [CoL_2 = N,N' - ethylene bis(1 - phenyl -- 3 methyl - 4 - benzlyliminepyra- zolone- 5 ligand Cobalt(II)] and its Oxygen adduct (CoL_2· Py· O_2· 2H_2O) were prepared and studies by mass spectroscope. The structure and Component of the Col_2, and CoL_2· Py· O_2· 2H_2O were determented by the method of mass spectroscope and other melhods.
出处 《云南民族学院学报(自然科学版)》 2000年第1期29-31,33,共4页 Journal of Yunnan University of The Nationalities(Natural Sciences Edition)
关键词 席夫碱 氧加合物 钴螯合物 四齿配件 Schiff base, complex, Oxygen adduct, Mass spectroscope, Study
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参考文献4

  • 1[1]Eric C.Niederhofier,James H.Timmons,and Arther E.Marter,Thermodynamics of Oxygen in Natural and Synthetic Dioxygen Complexs,Chem.Rev.,1984,84,137~203
  • 2[2]Robert D,Joties,David A.Summerville,and F.Basolo,Synthesis Oxygen Carrier Rlated to B1ological Systems,Chem.Rev.,1979,79(2),139~179
  • 3[6]Aluin L.Gumbliss and Fred Basolo,Monomeric Oxygen Adducts of N, N’ -Ethylenebis(acethlacetoniminato)Ligand Cobalt(Ⅱ)Preparation and Properties,J.Amer.Chem.Soc.,1970,92(1),55~60
  • 4[7]Brian M.Hoffman,Damon L.Diements,and Fred Basolo,Electron Paramagnetic Resonance studies of Some Cobalt(Ⅱ)Schiff Base Compounds and Their Monomeric Oxygen Adducts,J.Amer.Chem.Soc.,1970,92(1),61~65

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