摘要
用质谱测量方法对四齿配体席夫碱L1(L1=邻苯二胺缩-1-苯基-3-甲基-4-苯甲酸基吡唑啉酮-5)、CoL2(CoL2=乙二胺缩-1-苯基-3-甲基-4-苯甲酸基毗唑啉酮-5合钴(II)螯合物及其氧加合物(CoL2·Py·O2·2H2O)进行研究,与其它的分析、测定方法相结合,确定其组成和结构.
One tetradentate Schiff base L_1 (L_1 =N, N' -O-phenylene bis (1 -phenyl-3 -methyl-4- Benzoyliminephrazolone - 5) and Col_2 [CoL_2 = N,N' - ethylene bis(1 - phenyl -- 3 methyl - 4 - benzlyliminepyra- zolone- 5 ligand Cobalt(II)] and its Oxygen adduct (CoL_2· Py· O_2· 2H_2O) were prepared and studies by mass spectroscope. The structure and Component of the Col_2, and CoL_2· Py· O_2· 2H_2O were determented by the method of mass spectroscope and other melhods.
出处
《云南民族学院学报(自然科学版)》
2000年第1期29-31,33,共4页
Journal of Yunnan University of The Nationalities(Natural Sciences Edition)
关键词
席夫碱
氧加合物
钴螯合物
四齿配件
Schiff base, complex, Oxygen adduct, Mass spectroscope, Study